1.中国林业科学研究院木材工业研究所，北京 100091
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王鑫,管浩,戴鑫建等.木材/金属-有机框架复合材料研究进展[J].木材科学与技术,2023,37(01):8-17.
WANG Xin,GUAN Hao,DAI Xinjian,et al.Research Progress of Wood/Metal-Organic Frameworks Composites[J].Chinese Journal of Wood Science and Technology,2023,37(01):8-17.
金属-有机框架（metal-organic frameworks，MOFs）是一类由金属离子或团簇与有机配体组成的晶体材料，因其具有结构和功能多样性而备受关注。然而，MOFs的粉末结晶状态极大限制了其实际应用。木材作为一种天然多孔材料，具有有序的孔道结构、优良的力学性能和丰富的活性基团，是固定粉末状MOFs的理想载体。将MOFs与多孔木材复合构筑木材/MOFs复合材料，可实现MOFs功能特性与木材结构特点的有效结合，为拓展MOFs的应用潜力提供新途径。本文系统总结木材/MOFs复合材料的构筑策略，重点介绍木材/MOFs复合材料在液/气相吸附、催化、电化学储能等领域的最新应用进展，分析当前木材/MOFs复合材料研究中存在的问题以及未来的研究重点。
Metal-organic frameworks (MOFs) are an emerging crystal material consisting of inorganic metal ions/clusters and organic ligands, which have attracted much attention due to the structural and functional diversities. However, MOFs mainly exists in the form of powder and crystal because of their intrinsic crystalline nature, severely restricting the practical applications. As a naturally porous material, wood possesses an ordered pore structure, excellent mechanical properties, and rich active groups, making it an ideal carrier for the effective immobilization of powdery MOFs. Integrating MOFs with porous wood to form wood/MOFs composites can effectively combine the functional characteristic of MOFs and the structural features of wood, providing a new avenue to expand the application of MOFs. In this review, current state-of-the-art fabrication methods of wood/MOFs composites are systematically summarized. The latest applications in liquid/gas adsorption, catalysis, electrochemical energy storage, and other emerging fields are highlighted. In addition, current existing problems and future research directions in the field of wood/MOFs composites for advanced functional materials are discussed.
木材金属-有机框架复合材料载体
woodmetal-organic frameworkscompositecarrier
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