释香型无醛装饰纸饰面人造板性能评价
Performance Evaluation of Impregnated Paper Decorated Wood-Based Panels with Fragrance-Release Formaldehyde-Free Resin
- 2022年36卷第3期 页码:52-57
DOI: 10.12326/j.2096-9694.2021152
扫 描 看 全 文
1.中国林业科学研究院木材工业研究所,北京 100091
2.上海香料研究所,上海 200232
扫 描 看 全 文
梁敏,徐建峰,刘如等.释香型无醛装饰纸饰面人造板性能评价[J].木材科学与技术,2022,36(03):52-57.
LIANG Min,XU Jian-feng,LIU Ru,et al.Performance Evaluation of Impregnated Paper Decorated Wood-Based Panels with Fragrance-Release Formaldehyde-Free Resin[J].Chinese Journal of Wood Science and Technology,2022,36(03):52-57.
为降低人造板基材异味对饰面板产品气味的影响,在装饰纸浸渍用无醛胶黏剂中添加不同质量分数(0.25%、0.50%、0.75%、1.00%)的香料,赋予装饰纸香味,探究香料添加量对无醛装饰纸饰面人造板香料缓释性能及表面性能的影响。采用傅里叶变换红外光谱分析仪(FTIR)、电子扫描显微镜(SEM)分别对浸渍胶黏剂、装饰纸的化学成分和装饰纸表面形貌进行测试和表征。结果表明:无醛装饰纸饰面人造板香料缓释性能较好,室温条件下90 d以后仍能释放出香味;香料与胶黏剂的相容性较好,未影响浸渍胶黏剂自身的性能。无醛装饰纸胶膜对香料粒子有适度的封闭作用,这有利于实现香料的缓释;同时饰面人造板的表面结合强度、表面耐水蒸气、表面耐污染腐蚀性能(丙酮)均达到GB/T 15102—2017《浸渍胶膜纸饰面纤维板和刨花板》的相关指标要求。
In order to reduce the peculiar smell of the wood-based panels, various contents (with ratios of 0.25%, 0.50%, 0.75%, 1.00%) of aromatic compound were added into the formaldehyde-free adhesive to prepare the formaldehyde-free decorative paper, which endowed the decorative paper with fragrance. The effects of different aromatic contents on the slow-release performance and surface properties of the formaldehyde-free decorative paper surfaced wood-based panels were investigated. The chemical composition of impregnated resin and the surface morphologies of decorative paper were tested and characterized by the Fourier infrared spectroscopy (FTIR) and electron scanning microscope (SEM). The results showed that the aromatic sustained-release performance of formaldehyde-free decorative paper veneer wood-based panels was fairly good. The fragrance released from the testing panels has been detected after 90 days at the room temperature. The aromatic compound was compatible with the adhesive. It did not affect the properties of the impregnated adhesive. The formaldehyde-free decorative paper adhesive film had a moderate sealing effect on aromatic particles, which contributed to the slow-release of fragrance. At the same time, the properties of the surface bonding strength, surface resistance to water vapor, and surface anti-pollution (acetone) of the decorative surfaced panels met the requirements of the standard GB/T 15102—2017 of ",Surface Decorated Fiberboard and Particleboard with Paper Impregnated Thermosetting Reins,".
无醛胶黏剂装饰纸释香饰面人造板
formaldehyde-free adhesivedecorative paperfragrance releasingsurface decorated wood-based panels
龙玲. 木材及其制品挥发性有机化合物释放及评价[M]. 北京: 科学出版社, 2012.
槐敏, 金春德, 张文标, 等. 微囊化薰衣草香型环保胶合板的研制[J]. 林业科技开发, 2013, 27(5): 108-111.
胡杨兵, 刘玉, 孙蕾, 等. 基于微胶囊技术的饰面胶合板释香特性[J]. 福建农林大学学报(自然科学版), 2021, 50(2): 283-288.
HU Y B, LIU Y, SUN L, et al. Aroma-releasing characteristics of plywood based on microcapsule technology[J]. Journal of Fujian Agriculture and Forestry University (Natural Science Edition), 2021, 50(2): 283-288.
王启繁. 饰面刨花板气味释放特性及环境因素影响研究[D]. 哈尔滨: 东北林业大学, 2018.
苗红. 缓释香精微胶囊的制备及其在装饰纸中的应用[D]. 天津市: 天津科技大学, 2012.
刘如, 徐建峰, 龙玲. 一种装饰纸用无醛浸渍胶黏剂及其制备方法: CN111501416A[P]. 2020-08-07.
徐建峰, 龙玲, 刘如. 一种无醛浸渍胶膜纸用胶黏剂及其制备方法: CN111411543A[P]. 2020-07-14.
龙玲, 徐建峰, 刘如. 一种浸渍胶膜纸饰面无醛人造板及其制备方法: CN111496948B[P]. 2021-10-22.
徐建峰,龙玲,刘如. 人造板饰面装饰纸无醛化研究现状[J]. 木材科学与技术, 2021, 35(2): 1-5.
XU J F, LONG L, LIU R. Research Status Review of Formaldehyde-Free Decorative Paper for Wood-Based Panels[J]. Chinese Journal of Wood Science and Technology, 2021, 35(2): 1-5.
LI X Y, LU X B, LIANG M, et al. Conversion of waste lignocellulose to furfural using sulfonated carbon microspheres as catalyst[J]. Waste Management, 2020, 108: 119-126.
LIU R, LIANG M, XU J F, et al. Dialdehyde starch reinforced polyacrylate-polyethylene glycol resin for impregnated decorative paper with improved toughness and ultra-low formaldehyde emission[J]. Industrial Crops and Products, 2022, 176: 114390.
QIANG T, HAN M, LI X. Synthesis, characterization and fluorescence performance of a novel SAF-based waterborne polyurethane[J]. Progress in Organic Coatings, 2018, 122: 248-254.
XU J F, LI X Y, LIU R, et al. Dialdehyde modified cellulose nanofibers enhanced the physical properties of decorative paper impregnated by aldehyde-free adhesive[J]. Carbohydrate Polymers, 2020, 250: 116941.
Wołosiak-Hnat A, Zych K, Mężyńska M, et al. The influence of type and concentration of inorganic pigments on the polyurethane adhesive properties and adhesion of laminates[J]. International Journal of Adhesion and Adhesives, 2019, 90: 1-8.
王耀西, 罗晓明. 聚氨酯工业的应用发展研究[J]. 化工管理, 2018(29): 10-11.
冯云, 屈伟, 刘美宏, 等. 三聚氰胺甲醛树脂增韧改性研究进展[J]. 木材科学与技术, 2022, 36(1): 17-21, 74.
FENG Y, QU W, LIU M H, et al. Research Review on Toughening Modification of Melamine Formaldehyde Resin [J]. Chinese Journal of Wood Science andTechnology, 2022, 36(1): 17-21, 74.
相关作者
相关机构
微信公众号