低温快速固化酚醛树脂的研究进展
Research Status Review of Low-Temperature Fast-Curing Phenol Formaldehyde Resin
- 2021年35卷第2期 页码:12-17
DOI: 10.12326/j.2096-9694.2020097
扫 描 看 全 文
1.北华大学材料科学与工程学院,吉林吉林 132013
扫 描 看 全 文
孙丕智,潘晴,徐文彪等.低温快速固化酚醛树脂的研究进展[J].木材科学与技术,2021,35(02):12-17.
SUN Pi-zhi,PAN Qing,XU Wen-biao,et al.Research Status Review of Low-Temperature Fast-Curing Phenol Formaldehyde Resin[J].Chinese Journal of Wood Science and Technology,2021,35(02):12-17.
传统酚醛树脂作为木材胶黏剂,在人造板工业生产中热压时所需温度较高、时间较长,影响生产效率和产品性能,研制低温快速固化的酚醛树脂胶黏剂具有现实意义。综述国内外酚醛树脂低温固化的研究进展,主要从改性树脂制备和使用固化剂两方面入手,分析间苯二酚、金属离子和尿素等化学改性酚醛树脂,以及单组分和复合型固化剂的作用机理,并对未来的研究方向提出建议。
Traditional phenol formaldehyde resin, as wood adhesive, needs high temperature and extended time to cure during hot pressing of the wood-based panel manufacturing. To improve the production efficiency and product performance, the low-temperature fast-curing phenol formaldehyde resin has been identified as an significant valuable process development. The research implemented domestically and internationally on the low-temperature curing phenol formaldehyde resin is reviewed. The review focus on the preparation of modification resin and the application of the curing agent. The mechanism of phenol formaldehyde resin modification by resorcinol, metal ions and urea were analyzed. The reaction process of single component and composite curing agent are also discussed respectively. Suggestions for future research are proposed.
木材胶黏剂酚醛树脂低温快速固化改性固化剂
wood adhesivesphenol formaldehyde resinlow-temperature fast-curingmodificationcuring agent
方鲲, 刘晓, 李军, 等. 环保型改性酚醛树脂胶的制备与性能[J].木材工业, 2004, 18(2): 12-14.
FANG K, LIU X, LI J, et al. Preparation and properties of an environmentally-friendly modified PF resin[J].China Wood Industry, 2004, 18(2): 12-14.
Bhandari G,Pandit R,Bhandari N L. Extraction and characterization of chitosan and preparation of nanocomposites with resorcinol formaldehyde resin[J].Journal of Nepal Chemical Society, 2018(39):53-61.
Zhang S,Xu T,Liu Q,et al. Cationic gemini surfactant-resorcinol-aldehyde resin and its application in the extraction of endocrine disrupting compounds from food contacting materials[J].Food Chemistry,2019,277(3): 407-413.
王东旭,陈泽明,张广鑫,等. 一种快速固化酚醛树脂胶黏剂的研制[J].化学与粘合,2016,38(6): 447-449.
WANG D X,CHEN Z M,ZHANG G X,et al. Study on fast-curing phenol-formaldehyde resin adhesive[J].Chemistry and Bonding,2016,38(6): 447-449.
李萍,吴义强,刘文杰,等. 间苯二酚-双醛淀粉-甲醛共缩聚树脂胶黏剂制备[J].高分子材料科学与工程,2019,35(1): 122-129.
LI P,WU Y Q,LIU W J,et al. Preparation of resorcinol-dialdehyde starch-formaldehyde copolycondensation resin adhesive[J].Polymer Materials Science and Engineering,2019,35 (1): 122-129.
罗文士. 间苯二酚-苯酚-甲醛树脂的研制与在胶合木梁上的应用[J].木材工业,1990,4(3): 14-19.
LUO W S. Thepreparation of resorcinol-phenol formaldehyde resin and its application in laminted wooden beams[J].China Wood Industry, 1990,4(3): 14-19.
薛刚,李坚辉,王磊,等. 中温固化耐高温酚醛树脂的制备及性能[J].材料工程,2016, 44(3): 35-39.
XUE G,LI J H,WANG L,et al. Preparation and properties of heat-resistant phenolic resin cured at medium temperature[J].Journal of Materials Engineering,2016, 44(3): 35-39.
黄燕,谭淑珍. 苯酚-间苯二酚-甲醛胶粘剂一步共缩聚合成的研究[J].化学工程师,2002(4): 16-18.
HUANG Y,TAN S Z. Study on one stage process condensation synthesis of phenol-resorcinol-formaldehyde adhesive[J].Chemical Engineer,2002(4): 16-18.
Deng P,Liu Y,Liu Y,et al. Preparation of phosphorus‐containing phenolic resin and its application in epoxy resin as a curing agent and flame retardant[J].Polymers for Advanced Technologies,2018,29(4):1294-1302.
Rao M P R,Urmode T D,Shinde V S. Synthesis, characterization and cure behavior of phenol-crotonaldehyde-resorcinol resins[J].Materials Research Express,2019,6(11): 79-82.
柳婷. 间苯二酚改性酚醛树脂胶黏剂的制备及性能研究[D].长沙:中南林业科技大学,2014.
覃族,吴志平,吴姝云,等. 间苯二酚-苯酚-甲醛树脂胶粘剂的胶合工艺研究[J].热固性树脂,2016,31(2): 36-40.
QIN Z,WU Z P,WU S Y,et al. Study on the bonding process of resorcinol phenol formaldehyde resin adhesives[J].Thermosetting Resin,2016,31(2): 36-40.
张一甫,甘卫星. 共缩聚间苯二酚酚醛胶粘剂的合成研究[J].粘接,2002, 23(1): 19-21.
ZHANG Y F,GAN W X. Study on synthesis of a resorcinol Bakelite adhesive by condensation polymerization[J].Technology on Adhesion & Sealing,2002, 23(1): 19-21.
Zhou W,MA Jiahui,Yang J,et al. Controllable preparation and application of carbon spheres based on resorcinol-formaldehyde resin[J].Journal of Zhejiang Sci-Tech University(Natural Sciences Edition),2018,39(2): 163-170.
刘文杰,左迎峰,吴义强,等. 间苯二酚改性木材胶粘剂的研究进展[J].中国胶粘剂,2017,26(12):42-46.
LIU W J,ZUO Y F,WU Y Q,et al. Research progress of resorcinol modified wood adhesives[J].Chinese Adhesives,2017,26(12): 42-46.
Li J,Zhang J,Zhang S,et al. Alkali lignin depolymerization under eco-friendly and cost-effective NaOH/urea aqueous solution for fast curing bio-based phenolic resin[J].Industrial Crops and Products,2018(120):25-33.
Guo L,Zhang B,Wang Z,et al. Synthesis of functional ionic liquids as solvent for straw and application in modification of phenolic resin[J].Chinese Journal of Materials Research,2015,29(2):149-154.
PizziA. Pheonlic and tannin-based adhesive resins by reactions of coordinated metal ligands. I. phenolic chelates[J].Journal of Applied Polymer Science, 1979,24(5):1247-1255.
杨华,谭艺,赵斌,等. 金属离子催化剂对酚醛树脂分子结构及性能的影响[J].林产工业,2016,43(12):16-20.
YANG H,TAN Y,ZHAO B,et al. Effect of metal ion catalysts on phenolic resin molecular structure and property[J].China Forest Products Industry, 2016,43(12): 16-20.
于志龙. 酚醛树脂气凝胶及其衍生碳气凝胶的设计、制备及应用研究[D].合肥:中国科学技术大学,2017.
柳传宏,谢柳欣,左继成. 氢氧化钡催化合成可发性酚醛树脂的工艺研究[J].辽宁化工,2020,49(1):16-18.
LIU C H,XIE L X,ZUO J C. Study on synthesis process of foamable phenolic resol resin with Barium hydroxide catalyst[J].Liaoning Chemical Industry,2020,49 (1): 16-18.
Li J Y,Tang B J,Tu J B,et al. Effects of the addition of nano-MnO2 on in situ catalytic formation of carbon nanotubes during the coking of phenolic resin[J].Journal of the Ceramic Society of Japan,2019,127(4):191-198.
陈章敏. 基于二价金属离子催化的酚醛树脂固化温度调控及应用研究[D].长沙:中南林业科技大学,2019.
叶果,韩健,李翠翠. 催化剂对酚醛树脂胶粘剂基本性能的影响[J].广东化工,2008, 35(3):24-26.
YE G,HAN J,LI C C. Influence of activator on basic performance of PF resin adhesives[J].Guangdong Chemical Industry,2008, 35(3): 24-26.
王健. 二价金属离子催化浸渍纸用快速固化酚醛树脂的研究[D].哈尔滨:东北林业大学,2012.
欧亚男. 酚醛树脂胶粘剂低温快速固化研究[D].北京:北京林业大学,2007.
莫弦丰.二价金属氧化物催化合成高邻位苯酚-尿素-甲醛树脂及其性能研究[D].北京:中国林业科学研宄院, 2014.
Pizzi A,Stephanou A,Antunes I,et al. Alkaline PF resins linear extension by urea condensation with hydroxybenzylalcohol groups[J].Journal of Applied Polymer Science,1993,50(12):2201-2207.
雷洪,杜官本,PIZZI Antonio,等. 苯酚-尿素-甲醛共缩聚树脂结构形成比较[J].林产化学与工业, 2009, 29(1):73-78.
LEI H,DU G B,Antoniopizzi,et al. Comparison of structure formation of phenol-urea-formaldehyde resin[J].Chemistry and Industty of Forest Products,2009,29(1): 73-78.
王雅珍,王杰. 化学改性耐高温酚醛树脂研究进展[J].广州化工,2020,48(6):24-26.
WANG Y Z,WANG J. Research progress on chemically modified high temperature resistant phenolic resin[J].Guangzhou Chemical Industry,2020,48(6): 24-26.
时君友,韩忠军. 尿素改性酚醛树脂胶粘剂的研究[J].粘接,2006,27(1):15-17.
SHI J Y,HAN Z J. Study on urea-modified phenol formaldehyde resin adhesive[J].Adhesion in China,2006,27(1): 15-17.
陶毓博,李鹏,陆仁书,等. 尿素改性酚醛树脂胶粘剂的研究[J].林产工业,2005, 32(1):13-16.
TAO Y B,LI P,LU R S,et al. Study on urea-modified phenol formaldehyde resin adhesive[J].China Forest Products Industry, 2005, 32(1): 13-16.
曹明. 酚醛树脂及苯酚-尿素-甲醛共缩聚树脂合成反应机理研究[D].南京:南京林业大学, 2017.
王洪艳,李琴,张建,等. 苯酚-尿素-甲醛共缩聚树脂加速固化的研究[J].粘接,2016,37(12):36-38.
WANG H Y,LI Q,ZHANG J,et al. Study of curing acceleration of phenol-urea-formaldehyde co-condensed resin[J].Adhesion,2016,37(12): 36-38.
Laza J M,Vilas J L,RodríguezM, et al. Analysis of the crosslinking process of a phenolic resin by thermal scanning rheometry[J].Journal of Applied Polymer Science,2002,83(1):57-65.
Park B D,Riedl B, Kim Y S,et al. Effect of synthesis parameters on thermal behavior of phenol -formaldehyde resolresin[J].Journal of Applied Polymer Science,2002,83(7): 1415-1424.
黄剑峰,陈奶荣,林巧佳,等. 碳酸丙烯酯固化剂对酚醛树脂固化性能的影响[J].福建农林大学学报(自然科学版),2014,43(1):97-100.
HUANG J F,CHEN N R,LIN Q J,et al. Effects of the curing agent of propylene carbonate on the properties of phenolic formaldehyde resin[J].Journal of Fujian Agriculture and Forestry University (Natural Science Edition),2014,43(1): 97-100.
莫弦丰, 范东斌, 秦特夫, 等. 3种添加剂对酚醛树脂固化性能的影响[J].木材工业, 2014, 28(4): 9-12.
MO X F, FAN D B, QIN T F, et al. Influence of three additives on curing properties of phenol-formaldehyde resin[J].China Wood Industry, 2014, 28(4): 9-12.
刘胜平,季庆娟,马源,等. 酚醛树脂/木粉复合体系的固化行为研究[J].宁波职业技术学院学报,2006, 10(5):1-3, 10.
LIU S P,JI Q J,MA Y,et al. Study on curing behaviors for phenolic resins/wood flour system[J].Journal of Ningbo Polytechnic College,2006, 10(5): 1-3, 10.
林干,李炯炯,郭黎明,等. 酚醛树脂低温快速固化剂的开发与分析[J].林产工业,2016,43(10):20-24.
LIN G,LI J J,GUO L M,et al. Development and analysis of the fast curing agent for phenolic resin at low temperature[J].China Forest Products Industry, 2016,43(10): 20-24.
莫弦丰,范东斌,秦特夫,等. 复合固化剂对于酚醛树脂快速固化的影响[J].林产工业,2014,41(2):15-18.
MO X F,FAN D B,QIN T F,et al. Influence of composite additives on curing properties of phenol-formaldehyde resin[J].China Forest Products Industry,2014,41(2): 15-18.
李龙梓,邱建华,许霞. 热固性酚醛树脂固化剂研究[J].精细石油化工进展,2015,16(4):51-53.
LI L Z,QIU J H,XU X. Study on curing agent in thermosetting phenolic resin[J].Advances in Fine Petrochemicals,2015,16(4): 51-53.
Weng Z,Hu Y,Qi Y,et al. Enhanced properties of phthalonitrile resins under lower curing temperature via complex curing agent[J].Polymers for Advanced Technologies,2020,31(2): 233-239.
陈玉竹,储富祥,范东斌,等. 复合型酚醛树脂固化剂的研究[J].南京林业大学学报(自然科学版),2015,39(1):109-113.
CHEN Y Z,CHU F X,FAN D B,et al. Study on fast curing PF resin added by compound curing agent[J].Journal of Nanjing Forestry University (Natural Science Edition), 2015,39(1): 109-113.
相关作者
相关机构
微信公众号