Biomimetic Construction of Colored Superhydrophobic Wood Surface and Its Color Regulation

LIU Min; LI Lei; DENG Song-lin; JIA Shan-shan; WU Yi-qiang; QING Yan

doi:10.12326/j.2096-9694.2022109

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Biomimetic Construction of Colored Superhydrophobic Wood Surface and Its Color Regulation
1.School of Materials Science and Engineering，Central South University of Forestry and Technology，Changsha 410004，Hunan，China
Vol. 36, Issue 6, Pages: 61-69(2022)
DOI： 10.12326/j.2096-9694.2022109

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刘敏,李蕾,邓松林等.木材彩色超疏水表面仿生构建及其颜色调控[J].木材科学与技术,2022,36(06):61-69.

LIU Min,LI Lei,DENG Song-lin,et al.Biomimetic Construction of Colored Superhydrophobic Wood Surface and Its Color Regulation[J].Chinese Journal of Wood Science and Technology,2022,36(06):61-69.
刘敏,李蕾,邓松林等.木材彩色超疏水表面仿生构建及其颜色调控[J].木材科学与技术,2022,36(06):61-69. DOI： 10.12326/j.2096-9694.2022109.

LIU Min,LI Lei,DENG Song-lin,et al.Biomimetic Construction of Colored Superhydrophobic Wood Surface and Its Color Regulation[J].Chinese Journal of Wood Science and Technology,2022,36(06):61-69. DOI： 10.12326/j.2096-9694.2022109.

摘要

针对目前超疏水木材颜色单一以及构建方法不够环保等问题，提出一种基于金属氧化物的彩色超疏水涂层的绿色构建方法，以实现彩色超疏水木材的构建以及木材表面颜色的调控。选取杉木为研究对象，将具有不同颜色的金属氧化物与聚二甲基硅氧烷（PDMS）在水溶剂中共混制备涂料，涂覆在木材表面得到不同颜色的超疏水涂层，进一步通过调整涂料中金属氧化物的质量比调控颜色梯度。采用多种方法表征发现，涂饰木材的表面具有由粒子排列形成的微米/纳米分级仿生荷叶结构，水接触角大于150°。通过调整金属氧化物种类，成功制备9种不同颜色的超疏水木材，使木材具有超疏水性和颜色多样性。研究结果对拓展超疏水木材在装饰领域的使用范围具有重要意义，为彩色超疏水木材的构建提供理论依据。

Abstract

To improve color regulation of superhydrophobic wood with a sufficient green construction method, a colored superhydrophobic coating agent based on metal oxide was proposed to realize the construction of colored superhydrophobic wood and the surface of wood. Chinese fir (,Cunninghamia lanceolata,) was chosen as the research object to establish a superhydrophobic surface. Superhydrophobic coatings with different colors were prepared by simply mixing metal oxides of various colors with polydimethylsiloxane (PDMS) in an aqueous solvent. The color gradient control of colored superhydrophobic wood was achieved by adjusting the mass ratio of different metal oxides. It was found that the treated wood had good superhydrophobic properties. Its surface had a micron-and nanometer-scale hierarchical bionic lotus leaf surface structure formed by particle arrangement. The contact angle of water droplets was more than 150°. By changing the types of metal oxides, nine kinds of colored superhydrophobic wood with different colors were successfully prepared. Superhydrophobic colored coatings conferred super-hydrophobicity and color diversity on the wood. This research findings significantly expand the application of superhydrophobic wood in the decorative field and provid the theoretical basis and reference for the construction of colored superhydrophobic wood.

关键词

木材彩色超疏水表面金属氧化物颜色调控

Keywords

woodcolored superhydrophobic surfacesmetal oxidescolor regulation

references

孙庆丰, 杨玉山, 党宝康, 等. 仿生超疏水木材表面微纳结构制备研究进展[J]. 林业工程学报, 2021, 6(2): 1-11.

SUN Q F, YANG Y S, DANG B K, et al. Research progress of the preparation of biomimetic superhydrophobic wood surface micro-nano structures[J]. Journal of Forestry Engineering, 2021, 6(2): 1-11.

李国滨, 刘海峰, 李金辉, 等. 超疏水材料的研究进展[J]. 高分子材料科学与工程, 2020(12):142-150.

LI G B, LIU H F, LI J H, et al. Progress in research of preparation of superhydrophobic[J]. Polymer Materials Science & Engineering, 2020(12):142-150.

王玉峰, 李玉磊, 滕玉红, 等. 涂布法构建纸基绿色牢固超疏水表面[J]. 数字印刷, 2020(6): 69-76.

WANG Y F, LI Y L, TENG Y H, et al. Eco-friendly and robust superhydrophobic surface fabrication on paper substrate by roll coating[J]. Digital Printing, 2020(6): 69-76.

鲍艳, 畅菁香. 耐久型超疏水表面的研究进展[J]. 化工进展, 2020, 39(12): 5148-5160.

BAO Y, CHANG J X. Research progress of durable superhydrophobic surface[J]. Chemical Industry and Engineering Progress, 2020, 39(12): 5148-5160.

郗盼毅, 吴琳, 黄效华, 等. 绿色无氟超疏水材料研究进展[J]. 山东化工, 2020, 49(19): 66-67.

XI P Y, WU L, HUANG X H, et al. Research progress of green fluorine-free superhydrophobic materials[J]. Shandong Chemical Industry, 2020, 49(19): 66-67.

郝李伟, 董如林, 陈智栋, 等. 超疏水仿生氧化锌纳米棒阵列薄膜的合成[J]. 化工新型材料, 2020, 48(11): 69-71, 76.

HAO L W, DONG R L, CHEN Z D, et al. Synthesis of superhydrophobic biomimetic ZnO nanorod array film[J]. New Chemical Materials, 2020, 48(11): 69-71, 76.

鲍恩泉, 陈劲松, 姜凌云, 等. 仿生超疏水表面的制备与应用研究进展[J]. 材料保护, 2020, 53(6): 127-131, 143.

BAO E Q, CHEN J S, JIANG L Y, et al. Preparation, application and research progress of biomimetic superhydrophobic surface[J]. Materials Protection, 2020, 53(6): 127-131, 143.

祁元春, 徐光, 韩雪萍. 仿生超疏水表面的制备及应用进展[J]. 周口师范学院学报, 2020, 37(2): 82-85.

QI Y C, XU G, HAN X P. Progress in preparation and application of biomimetic superhydrophobic surface[J]. Journal of Zhoukou Normal University, 2020, 37(2): 82-85.

曹颐戬, 王聪, 王丽琴. 仿生超疏水材料及其在文物保护中的应用综述[J]. 材料导报, 2020, 34(3): 184-190.

CAO Y J, WANG C, WANG L Q. A review of bioinspired superhydrophobic materials and their applications in heritage conservation[J]. Materials Reports, 2020, 34(3): 184-190.

潘瑞, 钟敏霖. 超快激光制备超疏水超亲水表面及超疏水表面机械耐久性[J]. 科学通报, 2019, 64(12): 1268-1289.

PAN R, ZHONG M L. Fabrication of superwetting surfaces by ultrafast lasers and mechanical durability of superhydrophobic surfaces[J]. Chinese Science Bulletin, 2019, 64(12): 1268-1289.

任猛, 李永升, 胡歆, 等. 超疏水纳米复合涂层表面机械稳定性研究进展[J]. 塑料工业, 2019, 47(3): 8-13.

REN M, LI Y S, HU X, et al. Research progress on mechanical stability of super hydrophobic nanocomposite coatings[J]. China Plastics Industry, 2019, 47(3): 8-13.

马国佳, 刘星, 张伟, 等. 超疏水仿生表面制造及其应用[J]. 稀有金属材料与工程, 2018, 47(6): 1866-1871.

MA G J, LIU X, ZHANG W, et al. Fabrication and application of super-hydrophobic bionic surface[J]. Rare Metal Materials and Engineering, 2018, 47(6): 1866-1871.

叶向东, 蔡东宝, 侯俊文, 等. 超疏水、自清洁涂层对建筑墙体的防护[J]. 复合材料学报, 2018, 35(12): 3271-3279.

YE X D, CAI D B, HOU J W, et al. Superhydrophobic and self-cleaning coating for building wall protection[J]. Acta Materiae Compositae Sinica, 2018, 35(12): 3271-3279.

崔日俊, 秦静, 屈钧娥, 等. 彩色超疏水不锈钢表面的制备[J]. 表面技术, 2018, 47(2): 30-35.

CUI R J, QIN J, QU J E, et al. Preparation of super-hydrophobic colored surface on a stainless steel matrix[J]. Surface Technology, 2018, 47(2): 30-35.

王成臣, 张靓. 彩色超疏水纳米纤维膜的制备与研究[J]. 中国科技论文, 2017, 12(22): 2607-2611.

WANG C C, ZHANG L. Preparation and characterization of colored superhydrophobic nanofibrous mats[J]. China Sciencepaper, 2017, 12(22): 2607-2611.

孙晶, 周强, 任元, 等. 铝基彩色超疏水表面制备[J]. 电加工与模具, 2015(5): 35-37.

SUN J, ZHOU Q, REN Y, et al. Fabrication of color superhydrophobic surfaces on Al substrates[J]. Electromachining ＆ Mould, 2015(5): 35-37.

郝全勇, 李杰, 张静, 等. 水性超疏水涂料制备及涂层抗结冰性能研究[C]. 中国化学会高分子学科委员会. 2015年全国高分子学术论文报告会论文摘要集. 中国化学会高分子学科委员会: 中国化学会, 2015:215.

YANG Y S, SHAN L, SHEN H J, et al. Manufacturing of robust superhydrophobic wood surfaces based on PEG-Functionalized SiO2/PVA/PAA/Fluoropolymer hybrid transparent coating[J]. Progress in Organic Coatings, 2021, 154: 106186.

郭升亮, 田永庆, 韩媛媛, 等. 超疏水材料的研究进展[J]. 化工管理, 2021(4): 80-81.

GUO S L, TIAN Y Q, HAN Y Y, et al. Research progress of superhydrophobic materials[J]. Chemical Enterprise Management, 2021(4): 80-81.

WANG N, WANG Q, XU S S, et al. Robust superhydrophobic wood surfaces with mechanical durability[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2021, 608: 125624.

MA T T, LI L P, MEI C T, et al. Construction of sustainable, fireproof and superhydrophobic wood template for efficient oil/water separation[J]. Journal of Materials Science, 2021, 56(9): 5624-5636.

YI Z D, ZHAO B, LIAO M R, et al. Fabrication of superhydrophobic wood surface by etching polydopamine coating with sodium hydroxide[J]. Coatings, 2020, 10(9): 847.

LI Y F, CHEN C J, SONG J W, et al. Strong and superhydrophobic wood with aligned cellulose nanofibers as a waterproof structural material[J]. Chinese Journal of Chemistry, 2020(8): 823-829.

WANG Y, TANG Z W, LU S C, et al. Superhydrophobic wood grafted by poly(2-(perfluorooctyl)ethyl methacrylate) via ATRP with self-cleaning, abrasion resistance and anti-mold properties[J]. Holzforschung, 2020, 74(8): 799-809.

LI Y F, CHEN C J, SONG J W, et al. Strong and superhydrophobic wood with aligned cellulose nanofibers as a waterproof structural material[J]. Chinese Journal of Chemistry,2020, 38(8).: 823-829

王小青, 孟军旺, 程志泳, 等. 木材耐久性超疏水表面构建研究进展[J]. 林业工程学报, 2020, 5(3): 13-20.

WANG X Q, MENG J W, CHENG Z Y, et al. Research progress of durable superhydrophobic wood surface[J]. Journal of Forestry Engineering, 2020, 5(3): 13-20.

HAN X S, WANG Z X, ZHANG Q Q, et al. A simple and efficient method to fabricate superhydrophobic wood with enhanced mechanical durability[J]. Forests, 2019, 10, 750

杨玉山, 沈华杰, 邱坚. 基于纳米SiO2-PDMS体系的耐磨超疏水木材表面构建与特性评价[J]. 西南林业大学学报(自然科学), 2019, 39(6): 160-166.

YANG Y S, SHEN H J, QIU J. Construction and characteristics of the mechanically robust superhydrophobic wood surface based on SiO2-PDMS coating[J]. Journal of Southwest Forestry University (Natural Sciences), 2019, 39(6): 160-166.

BAI X G, SHEN Y Q, TIAN H F, et al. Facile fabrication of superhydrophobic wood slice for effective water-in-oil emulsion separation[J]. Separation and Purification Technology, 2019, 210: 402-408.

朱凯, 秦静, 王海人, 等. 基于微纳米孔洞结构的彩色超疏水不锈钢表面的制备[J]. 电镀与精饰, 2018, 40(11): 37-41.

ZHU K, QIN J, WANG H Ret al. Preparation of coloured super hydrophobic stainless steel surface based on micro/nano hole structure[J]. Plating & Finishing, 2018(11):37-41.

贾闪闪. 基于气相辅助迁移法的木材超疏水表面稳定性调控与功能化修饰[D]. 长沙：中南林业科技大学, 2020

侯琳刚. 耐磨超疏水材料的制备及其耐久性能研究[D]. 西安：西安科技大学, 2018

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