吡唑醚菌酯制剂处理马尾松边材的防腐性能

张景朋; 邵闯; 马星霞; 蒋明亮

doi:10.12326/j.2096-9694.2026047

“南方储备林高效培育与绿色制造”专栏 | 浏览量 : 0 下载量: 4 CSCD: 0 CNKI被引量: 0 Crossref: 0 Wos: 0 Scopus: 0 更多指标

PDF
导出
分享
收藏
专辑

吡唑醚菌酯制剂处理马尾松边材的防腐性能
Decay Resistance of Pinus massoniana Sapwood Treated with Pyraclostrobin Formulation
中国林业科学研究院木材工业研究所，北京 100091
2026年40卷第4期页码：1-9
DOI： 10.12326/j.2096-9694.2026047
稿件说明：

移动端阅览

张景朋,邵闯,马星霞等.吡唑醚菌酯制剂处理马尾松边材的防腐性能[J].木材科学与技术,2026,40(04):1-9. DOI： 10.12326/j.2096-9694.2026047.

Zhang Jingpeng,Shao Chuang,Ma Xingxia,et al.Decay Resistance of Pinus massoniana Sapwood Treated with Pyraclostrobin Formulation[J].Chinese Journal of Wood Science and Technology,2026,40(04):1-9. DOI： 10.12326/j.2096-9694.2026047.

摘要

为提高马尾松（

Pinus massoniana

）人工林木材的耐腐性，利用吡唑醚菌酯（pyraclostrobin）水性制剂真空浸渍处理马尾松边材试样，依据LY/T 1283—2011《木材防腐剂对腐朽菌毒性试验室试验方法》对处理材室内耐腐性能和抗流失性能进行评价，并采用多种方法对处理前后马尾松边材的化学组分进行分析。结果表明：在吡唑醚菌酯载药量为0.25 kg/m

时，处理材被白腐菌和褐腐菌侵染后的质量损失率分别为2.94%和1.75%，比未处理材分别降低83.78%和92.91%，处理材耐腐性能优异。吡唑醚菌酯处理材在0.16 kg/m

和0.31 kg/m

载药量下防腐剂的流失率分别为10.1%和7.5%，高载药量处理材的流失率更低；傅里叶变换红外光谱分析显示吡唑醚菌酯处理材没有新的吸收峰出现，能谱和X射线光电子能谱分析表明吡唑醚菌酯处理改变了木材表面的元素原子百分比及碳元素的化学状态。研究结果为后续马尾松野外耐久性试验提供参考，推荐0.25 kg/m

作为室外试验条件下的吡唑醚菌酯参考载药量。

Abstract

To enhance the decay resistance of plantation-grown

Pinus massoniana

sapwood specimens were vacuum-impregnated with an aqueous pyraclostrobin formulation. According to LY/T 1283—2011 “

method of laboratory test for toxicity of wood preservatives to decay fungi

”

the decay resistance and leach resistance of the treated wood were evaluated

and changes in the chemical and surface characteristics of the wood after treatment were investigated by Fourier transform infrared spectroscopy (FTIR)

energy-dispersive X-ray spectroscopy (EDS)

and X-ray photoelectron spectroscopy (XPS). At a pyraclostrobin retention of 0.25 kg/m

the mass losses of treated specimens exposed to white rot and brown rot fungi were 2.94% and 1.75%

respectively

corresponding to reductions of 83.78% and 92.91% compared with untreated controls. These results demonstrated that pyraclostrobin treatment markedly improved the decay resistance of

Pinus massoniana

sapwood. At pyraclostrobin retentions of 0.16 and 0

.31 kg/m

the leaching rates were 10.1% and 7.5%

respectively

indicating lower proportional leaching at the higher retention. FTIR spectra showed no new characteristic absorption peaks after treatment

whereas EDS and XPS analyses revealed changes in the elemental composition and chemical states of carbon at the wood surface. Based on the laboratory decay test

a pyraclostrobin retention of 0.25 kg/m

was recommended as a reference level for subsequent field durability evaluation.

关键词

Keywords

references

孙芳利 , Prosper Nayebare Kakwara , 吴华平 , 等 . 木竹材防腐技术研究概述 [J ] . 林业工程学报 , 2017 , 2 ( 5 ): 1 - 8 .

Sun Fangli , Prosper Nayebare Kakwara , Wu Huaping , et al . A review on the development of wood and bamboo preservation [J ] . Journal of Forestry Engineering , 2017 , 2 ( 5 ): 1 - 8 .

Goodell B . Wood deterioration and preservation: advances in our changing world [M ] . Washington, DC : American Chemical Society , 2003 .

葛晓雯 , 王立海 , 侯捷建 , 等 . 褐腐杨木微观结构、力学性能与化学成分的关系研究 [J ] . 北京林业大学学报 , 2016 , 38 ( 10 ): 112 - 122 .

Ge Xiaowen , Wang Lihai , Hou Jiejian , et al . Relationship among microstructure, mechanical properties and chemical compositions in Populus cathayana sapwood during brown-rot decay [J ] . Journal of Beijing Forestry University , 2016 , 38 ( 10 ): 112 - 122 .

劳万里 , 段新芳 , 吕斌 , 等 . 碳达峰碳中和目标下木材工业的发展路径分析 [J ] . 木材科学与技术 , 2022 , 36 ( 1 ): 87 - 91 .

Lao Wanli , Duan Xinfang , Lyu Bin , et al . Development path of China wood industry under the targets of carbon dioxide emission peaking and carbon neutrality [J ] . Chinese Journal of Wood Science and Technology , 2022 , 36 ( 1 ): 87 - 91 .

曹金珍 . 国外木材防腐技术和研究现状 [J ] . 林业科学 , 2006 , 42 ( 7 ): 120 - 126 .

Cao Jinzhen . A review on wood preservation technologies and research [J ] . Scientia Silvae Sinicae , 2006 , 42 ( 7 ): 120 - 126 .

孙芳利 , 鲍滨福 , 陈安良 , 等 . 有机杀菌剂在木竹材保护中的应用及发展展望 [J ] . 浙江农林大学学报 , 2012 , 29 ( 2 ): 272 - 278 .

Sun Fangli , Bao Binfu , Chen Anliang , et al . Application and prospect of organic biocides in timber preservation [J ] . Journal of Zhejiang A & F University , 2012 , 29 ( 2 ): 272 - 278 .

张景朋 , 蒋明亮 , 马星霞 , 等 . 甲氧基丙烯酸酯类制剂的木材防腐性能研究 [J ] . 北京林业大学学报 , 2021 , 43 ( 3 ): 131 - 137 .

Zhang Jingpeng , Jiang Mingliang , Ma Xingxia , et al . Wood decay performance of strobilurins preservatives [J ] . Journal of Beijing Forestry University , 2021 , 43 ( 3 ): 131 - 137 .

蒋明亮 , 张卿硕 , 张景朋 , 等 . 环唑醇及氟环唑处理材的野外耐久性能评价 [J ] . 林业科学 , 2024 , 60 ( 6 ): 148 - 152 .

Jiang Mingliang , Zhang Qingshuo , Zhang Jingpeng , et al . Durability evaluation of wood treated with preservatives containing cyproconazole and epoxiconazole by field stake test [J ] . Scientia Silvae Sinicae , 2024 , 60 ( 6 ): 148 - 152 .

曹金珍 . 木材保护剂分散体系及其液体渗透性研究概述 [J ] . 林业工程学报 , 2019 , 4 ( 3 ): 1 - 9 .

Cao Jinzhen . A review on wood protectant dispersion systems and their liquid penetration [J ] . Journal of Forestry Engineering , 2019 , 4 ( 3 ): 1 - 9 .

赵培亮 . 新型Strobilurins衍生物的设计、合成及生物活性研究 [D ] . 武汉 : 华中师范大学 , 2008 .

Bartlett D W , Clough J M , Godwin J R , et al . The strobilurin fungicides [J ] . Pest Management Science , 2002 , 58 ( 7 ): 649 - 662 .

Zhang J P , Jiang M L , Zhang B , et al . Mold and stain resistance of bamboo treated with pyraclostrobin fungicide [J/OL ] . Polymers , 2022 , 14 ( 24 ): 5537 . https://doi.org/10.3390/polym14245537 https://doi.org/10.3390/polym14245537 .

袁承志 , 张振 , 郑一 , 等 . 33年生马尾松木材力学性质种源变异研究 [J ] . 中南林业科技大学学报 , 2021 , 41 ( 8 ): 68 - 74, 107 .

Yuan Chengzhi , Zhang Zhen , Zheng Yi , et al . Variation of wood mechanical properties of 33-year-old Pinus massoniana from different provenances [J ] . Journal of Central South University of Forestry & Technology , 2021 , 41 ( 8 ): 68 - 74, 107 .

秦理哲 , 杨章旗 , 段文贵 , 等 . 马尾松防腐材胶合性能的径向变异研究 [J ] . 林业工程学报 , 2021 , 6 ( 3 ): 69 - 73 .

Qin Lizhe , Yang Zhangqi , Duan Wengui , et al . Radial variation in bonding performance of preservative-treated Pinus massoniana wood [J ] . Journal of Forestry Engineering , 2021 , 6 ( 3 ): 69 - 73 .

张景朋 , 蒋明亮 , 马星霞 , 等 . 一种微乳液型木竹材防腐剂及其制备方法 : CN202011392792.3 [P ] . 2021-03-12 .

张景朋 , 邵闯 , 蒋明亮 . 高效液相色谱法测定防腐材中嘧菌酯含量的方法研究 [J ] . 木材科学与技术 , 2025 , 39 ( 1 ): 64 - 70 .

Zhang Jingpeng , Shao Chuang , Jiang Mingliang . Measurement of the azoxystrobin content in preservative-treated wood by high performance liquid chromatography [J ] . Chinese Journal of Wood Science and Technology , 2025 , 39 ( 1 ): 64 - 70 .

朱愿 . 异噻唑啉酮微乳液型木材防腐体系构建及性能 [D ] . 北京 : 北京林业大学 , 2017 .

李晓文 , 席丽霞 , 蒋明亮 . 5种三唑微乳液及其铜胺制剂的抗流失性能 [J ] . 林业科学 , 2017 , 53 ( 3 ): 147 - 153 .

Li Xiaowen , Xi Lixia , Jiang Mingliang . The leachability of five kinds of triazoles and their copper triazole formulations [J ] . Scientia Silvae Sinicae , 2017 , 53 ( 3 ): 147 - 153 .

席丽霞 . 三唑类木材防腐剂的制备及其性能研究 [D ] . 北京 : 中国林业科学研究院 , 2014 .

Zhang J , Kamdem D P . FTIR characterization of copper ethanolamine-wood interaction for wood preservation [J ] . Holzforschung , 2000 , 54 ( 2 ): 119 - 122 .

Kartal S N , Brischke C , Rapp A O , et al . Biological effectiveness of didecyl dimethyl ammonium tetrafluoroborate (DBF) against basidiomycetes following preconditioning in soil bed tests [J ] . Wood Science and Technology , 2006 , 40 ( 1 ): 63 - 71 .

李改云 , 任海青 , 秦特夫 , 等 . 茯苓褐腐过程中木材化学成分的变化 [J ] . 林业科学研究 , 2009 , 22 ( 4 ): 592 - 596 .

Li Gaiyun , Ren Haiqing , Qin Tefu , et al . Changes of main wood chemical components during brown-rot decay by Wolfiporia cocos [J ] . Forest Research , 2009 , 22 ( 4 ): 592 - 596 .

李权 , 齐文玉 , 任凯 , 等 . 基于XPS的马尾松褐腐降解研究 [J ] . 西南林业大学学报(自然科学) , 2018 , 38 ( 3 ): 188 - 193 .

Li Quan , Qi Wenyu , Ren Kai , et al . Biodegradation of Pinus massoniana by brown-rot fungi based on X-ray photoelectron spectroscopy [J ] . Journal of Southwest Forestry University (Natural Sciences) , 2018 , 38 ( 3 ): 188 - 193 .