漂白-浸渍-热压协同改性泡桐木材的制备及性能表征

梁博楠; 张坤; 刘苏玲; 刘小桢; 李雪琪; 樊雪勤; 张杨; 甘文涛

doi:10.12326/j.2096-9694.2025058

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漂白-浸渍-热压协同改性泡桐木材的制备及性能表征
Preparation and Performance Characterization of Paulownia Wood Modified Using Bleaching-Impregnation-Hot Pressing Synergistic Method
东北林业大学材料科学与工程学院，生物质材料科学与技术教育部重点实验室，黑龙江哈尔滨 150040
2025年39卷第6期页码：43-52
DOI： 10.12326/j.2096-9694.2025058
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梁博楠,张坤,刘苏玲等.漂白-浸渍-热压协同改性泡桐木材的制备及性能表征[J].木材科学与技术,2025,39(06):43-52. DOI： 10.12326/j.2096-9694.2025058.

LIANG Bonan,ZHANG Kun,LIU Suling,et al.Preparation and Performance Characterization of Paulownia Wood Modified Using Bleaching-Impregnation-Hot Pressing Synergistic Method[J].Chinese Journal of Wood Science and Technology,2025,39(06):43-52. DOI： 10.12326/j.2096-9694.2025058.

摘要

以白花泡桐（

Paulownia fortunei

）木材为研究对象，采用过氧化氢漂白处理，增加木材细胞壁的活性基团数量；利用壳聚糖溶液（质量分数4%）在木材细胞壁上负载有机层，通过涂覆硅酸钠溶液（质量分数40%）形成改性层，在80 ℃和5 MPa的热压条件下固化获得协同改性木材。与天然木材相比，在增重率为18.9%、压缩率为75%时，协同改性木材的拉伸、抗弯强度和硬度分别提升259%、122%和75%；垂直燃烧等级达到V-0级，极限氧指数高达50.1%，热释放速率峰值降低60.1%，总热释放量和总

烟释放量分别减少44.7%和95.1%，一氧化碳释放量下降31.2%；对黑曲霉的防治效力可达100%。该研究为改善速生材材质提供新途径，制备的改性木材在防火安全工程和结构建筑领域具有潜在的应用价值。

Abstract

Paulownia fortunei

suffers from insufficient tensile strength

high flammability

and susceptibility to mold

which severely limit its application in furniture and architectural decoration materials. To address these issues

this study proposes a synergistic method combing bleaching

impregnation

and hot pressing. First

Paulownia fortunei

was bleached with 30% hydrogen peroxide(H

) for 3 hours

preserving its natural porous structure and partial lignin content while increasing interfacial binding sites. The bleached wood was subsequently immersed in a 4% chitosan (CS) solution under a vacuum of －0.1 MPa for 30 minutes. Afterwards

a 40% sodium silicate (Na

SiO

) solution was uniformly applied to the wood surface. Finally

the impregnated wood was cured and densified through hot pressing at 80 ℃ under 5 MPa. The modified wood showed increases in tensile strength

bending strength and hardness of 259%

122% and 75%

respectively

compared to natural wood

with a weight gain of 18.9% and a compression rate of 75%. Regarding flame retardancy

the vertical burning rating reached V-0

the limiting oxygen index (LOI) was 50.1%

the peak heat release rate (HRR) decreased by 60.1%

total heat release (THR) and total smoke release (TSR) decreased by 44.7% and 95.1%

respectively

and carbon monoxide release (COP) decreased by 31.2%. In terms of anti-corrosion performance

this material can effectively resist

Aspergillus niger

with the mold-infected area of 0

achieving 100% mold control efficiency (MCE). This study provided a novel approach for improving the quality of fast-growing wood

and the resulting modified wood shows significant potential for applications in fire safety engineering and structural construction.

关键词

Keywords

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