碳点制备及其在木质功能材料领域应用研究进展

张龙飞; 宋纪元; 吕少一; 沈越岗; 周兆兵; 彭立民

doi:10.12326/j.2096-9694.2025057

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碳点制备及其在木质功能材料领域应用研究进展
Research Progress in Preparation of Carbon Dots and Theirs Application in Wood-based Functional Materials
1.中国林业科学研究院木材工业研究所，北京 100091
2.南京林业大学材料科学与工程学院，江苏南京 210037
2025年39卷第5期页码：20-31
DOI： 10.12326/j.2096-9694.2025057
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张龙飞,宋纪元,吕少一等.碳点制备及其在木质功能材料领域应用研究进展[J].木材科学与技术,2025,39(05):20-31. DOI： 10.12326/j.2096-9694.2025057.

ZHANG Longfei,SONG Jiyuan,LYU Shaoyi,et al.Research Progress in Preparation of Carbon Dots and Theirs Application in Wood-based Functional Materials[J].Chinese Journal of Wood Science and Technology,2025,39(05):20-31. DOI： 10.12326/j.2096-9694.2025057.

摘要

碳点因其典型的量子尺寸、优异的光学吸收与转换性质、良好的分散性和环保无毒等优点而备受关注。目前碳点的制备主要包括自上而下技术（如激光蚀刻法）和自下而上技术（如微波合成法、热裂解法和水热法）两类。其中，水热法制备碳点兼具原料来源广泛、制备方法简便、水分散性优异和表面易于功能化等优点，成为当前荧光碳纳米材料主流制备方法之一。综述归纳碳点主要制备方法、基本性质与形成机制，以及其在光催化、耐光老化、阻燃防火、抗菌和改性胶黏剂等木质功能材料领域的应用，并对碳点在新型木质功能材料研发方面的未来发展进行展望。

Abstract

Carbon dots have attracted significant attention due to their unique quantum size effect

excellent optical absorption and conversion properties

good dispersibility

and eco-friendly and non-toxic characteristics. The synthesis of carbon dots is generally categorized into top-down approaches (e.g.

laser ablation) and bottom-up methods (e.g.

microwave synthesis

pyrolysis

and hydrothermal treatment). Among these methods

hydrothermal treatment stands out for its adaptability to broad raw material sources

simple preparation process

excellent water dispersibility

and facile surface functionalization

making it one of the mainstream methods for preparing fluorescent carbon nanomaterials. This review summarizes the main preparation methods

basic properties

and formation mechanisms of fluorescent carbon dots

as well as their applications in the fields of wood-based functional materials such as photocatalysis

photoaging resistance

flame retardancy

antibacterial performance and adhesives. The prospects for the development of carbon dots in novel wood-based functional materials are also proposed.

关键词

Keywords

references

王楚楚 , 叶韧 , 史霄宇 , 等 . 木质素基碳点的制备及其对pH响应分析 [J ] . 林产化学与工业 , 2024 , 44 ( 4 ): 107 - 112 .

WANG C C , YE R , SHI X Y , et al . Preparation of lignin based carbon dots and their pH response analysis [J ] . Chemistry and Industry of Forest Products , 2024 , 44 ( 4 ): 107 - 112 .

梁倩 , 王贵龙 , 蔡政汉 , 等 . 氧化法制备荧光碳点及其应用 [J ] . 林产化学与工业 , 2018 , 38 ( 3 ): 90 - 96 .

LIANG Q , WANG G L , CAI Z H , et al . Preparation of fluorescent carbon dots by oxidation method and its application [J ] . Chemistry and Industry of Forest Products , 2018 , 38 ( 3 ): 90 - 96 .

刘一繁 , 姜宇 , 韩有奇 , 等 . 生物质基绿色荧光N掺杂碳点的制备及分析 [J ] . 林产化学与工业 , 2021 , 41 ( 2 ): 79 - 85 .

LIU Y F , JIANG Y , HAN Y Q , et al . Preparation and analysis of biomass based green fluorescent N-doped carbon dots [J ] . Chemistry and Industry of Forest Products , 2021 , 41 ( 2 ): 79 - 85 .

SHI W Q , HAN Q R , WU J J , et al . Synthesis mechanisms, structural models, and photothermal therapy applications of top-down carbon dots from carbon powder, graphite, graphene, and carbon nanotubes [J ] . International Journal of Molecular Sciences , 2022 , 23 ( 3 ): 1456 .

王颖 , 安邦 , 徐明聪 , 等 . 水热-硝酸氧化合成发蓝光和绿光木质素基碳点的研究 [J ] . 林产化学与工业 , 2022 , 42 ( 4 ): 33 - 39 .

WANG Y , AN B , XU M C , et al . Study on the synthesis of blue and green light emitting lignin based carbon dots by hydrothermal nitric acid oxidation [J ] . Chemistry and Industry of Forest Products , 2022 , 42 ( 4 ): 33 - 39 .

XIANG T F , WANG J Q , LIANG Y L , et al . Carbon dots for anti-corrosion [J ] . Advanced Functional Materials , 2024 , 34 ( 48 ): 2411456 .

ZHU S J , SONG Y B , ZHAO X H , et al . The photoluminescence mechanism in carbon dots (graphene quantum dots, carbon nanodots, and polymer dots): Current state and future perspective [J ] . Nano Research , 2015 , 8 ( 2 ): 355 - 381 .

SHARON M , MISHRA N , PATIL B , et al . Conversion of polypropylene to two-dimensional gra phene, one-dimensional carbon nano tubes and zero-dimensional C-dots, all exhibiting typical sp 2 -hexagonal carbon rings [J ] . IET Circuits , Devices & Systems, 2015 , 9 ( 1 ): 59 - 66 .

张龙飞 , 杨博涵 , 彭立民 , 等 . 功能化碳纳米点在木材表面耐光老化的应用研究 [J ] . 木材科学与技术 , 2024 , 38 ( 5 ): 21 - 31 .

ZHANG L F , YANG B H , PENG L M , et al . Application of functionalized carbon nanodots in light aging resistance of wood surface [J ] . Wood Science and Technology , 2024 , 38 ( 5 ): 21 - 31 .

张龙飞 , 海日汗 , 王思群 , 等 . 碳量子点复合TiO 2 木材涂层制备及其净化甲醛气体的研究 [J ] . 北京林业大学学报 , 2022 , 44 ( 1 ): 113 - 122 .

ZHANG L F , HAI R H , WANG S Q , et al . Preparation of carbon quantum dots composite TiO 2 wood coating and its purification of formaldehyde gas [J ] . Journal of Beijing Forestry University , 2022 , 44 ( 1 ): 113 - 122 .

ZHANG L F , PENG L M , LIANG S Q , et al . Poly(vinyl alcohol)/nanocellulose film integrated with phenolic waste-based carbon dots for ultraviolet-blocking and flame retardant applications [J ] . Progress in Organic Coatings , 2023 , 184 : 107872 .

CHEN J , LI T , LIN C Z , et al . Green synthesis of red-emitting carbon dots for bioimaging, sensing, and antibacterial applications [J ] . Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy , 2025 , 328 : 125458 .

CHEN S Q , LI X Y , BAI M Y , et al . Oyster-inspired carbon dots-functionalized silica and dialdehyde chitosan to fabricate a soy protein adhesive with high strength, mildew resistance, and long-term water resistance [J ] . Carbohydrate Polymers , 2023 , 319 : 121093 .

BALAKRISHNAN T , ANG W L , MAHMOUDI E , et al . Formation mechanism and application potential of carbon dots synthesized from palm kernel shell via microwave assisted method [J ] . Carbon Resources Conversion , 2022 , 5 ( 2 ): 150 - 166 .

ZHU P P , CHENG Z , DU L L , et al . Synthesis of the Cu-doped dual-emission fluorescent carbon dots and its analytical application(article) [J ] . Langmuir , 2018 , 34 ( 34 ): 9982 - 9989 .

TORRISI L , SILIPIGNI L , TORRISI A , et al . Luminescence in laser-generated functionalized carbon dots [J ] . Optics & Laser Technology , 2024 , 177 : 111089 .

VENUGOPALAN P , VIDYA N . Microwave-assisted green synthesis of carbon dots derived from wild lemon ( Citrus pennivesiculata ) leaves as a fluorescent probe for tetracycline sensing in water [J ] . Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy , 2023 , 286 : 122024 .

MEHTA V N , JHA S , BASU H , et al . One-step hydrothermal approach to fabricate carbon dots from apple juice for imaging of mycobacterium and fungal cells [J ] . Sensors and Actuators B: Chemical , 2015 , 213 : 434 - 443 .

EGOROVA M , TOMSKAYA A , SMAGULOVA S A , et al . Optical properties of carbon dots synthesized by the hydrothermal method [J ] . Materials , 2023 , 16 ( 11 ): 4018 .

HAN Z , HE L , SHUANG P , et al . Hydrothermal synthesis of carbon dots and their application for detection of chlorogenic acid [J ] . Luminescence , 2020 , 35 ( 7 ): 989 - 997 .

XU Z , HUANG W , CHEN C , et al . Preparation of new full UV-absorbing carbon dots from quercetin and their application in UV-absorbing systems for waterborne polyurethane coatings [J ] . Materials Today Chemistry , 2023 , 27 : 101269 .

GHOSH T , NANDI S , BHATTACHARYYA S K , et al . Nitrogen and sulphur doped carbon dot: an excellent biocompatible candidate for in-vitro cancer cell imaging and beyond [J ] . Environmental Research , 2023 , 217 : 114922 .

LI X C , FU Y Z , ZHAO S J , et al . Metal ions-doped carbon dots: Synthesis, properties, and applications [J ] . Chemical Engineering Journal , 2022 , 430 ( 4 ): 133101 .

张龙飞 , 汪腾 , 王雅梅 , 等 . 异元素掺杂碳量子点制备及对木材阻燃性能的影响 [J ] . 林业工程学报 , 2022 , 7 ( 3 ): 31 - 39 .

ZHANG L F , WANG T , WANG Y M , et al . Preparation of carbon quantum dots doped with different elements and its effect on flame retardancy of wood [J ] . Journal of Forestry Engineering , 2022 , 7 ( 3 ): 31 - 39 .

HU S L , WEI Z J , CHANG Q , et al . A facile and green method towards coal-based fluorescent carbon dots with photocatalytic activity [J ] . Applied Surface Science , 2016 , 378 : 402 - 407 .

ZHANG L F , WANG Y , PENG L M , et al . Self-luminous wood coatings with carbon dots/TiO 2 grafted afterglow SrAl 2 O 4 : Eu, dy core-shell phosphors for long-lasting formaldehyde removal [J ] . Polymers , 2023 , 15 ( 9 ): 2077 .

CAILOTTO S , MASSARI D , GIGLI M , et al . N-doped carbon dot hydrogels from brewing waste for photocatalytic wastewater treatment [J ] . ACS Omega , 2022 , 7 ( 5 ): 4052 - 4061 .

PENG Z L , ZHOU Y Q , JI C Y , et al . Facile synthesis of "boron-doped" carbon dots and their application in visible-light-driven photocatalytic degradation of organic dyes [J ] . Nanomaterials , 2020 , 10 ( 8 ): 1560 .

韩有奇 , 倪佳馨 , 黄晓琳 , 等 . CQDs/TiO 2 的制备及光催化性能 [J ] . 林产化学与工业 , 2021 , 41 ( 5 ): 58 - 64 .

HAN Y Q , NI J X , HUANG X L , et al . Preparation and photocatalytic properties of CQDs/TiO 2 [J ] . Chemistry and Industry of Forest Products , 2021 , 41 ( 5 ): 58 - 64 .

胡靖怡 , 郑雅桐 , 叶炜浩 , 等 . N-杂环芳基水溶性碳点全光谱紫外吸收剂的合成与应用 [J ] . 应用化学 , 2023 , 40 ( 12 ): 1700 - 1711 .

HU J Y , ZHENG Y T , YE W H , et al . Synthesis and application of N-heterocyclic aryl water soluble carbon dots full spectrum UV absorbers [J ] . Applied Chemistry , 2023 , 40 ( 12 ): 1700 - 1711 .

EZATI P , Rhim J W . Pectin/carbon quantum dots fluorescent film with ultraviolet blocking property through light conversion [J ] . Colloids and Surfaces B: Biointerfaces , 2022 , 219 : 112804 .

QIU J M , YE W H , CHEN C C , et al . Toward efficient broad-spectrum UV absorption of carbon dots: facile preparation, performance characterization and its application as UV absorbers [J ] . Journal of Industrial and Engineering Chemistry , 2023 , 117 : 442 - 449 .

XU R , GAN J , WANG J , et al . Photoluminescent transparent wood with excellent UV-shielding function [J ] . ACS Omega , 2024 , 9 ( 7 ): 8092 - 8102 .

YU S J , LU S Y , TAN D F , et al . Nitrogen and phosphorus co-doped carbon dots for developing highly flame retardant poly (vinyl alcohol) composite films [J ] . European Polymer Journal , 2022 , 164 : 110970 .

TAHER R A , ZAHRA S , SHARIATINIA Z , et al . Nitrogen and phosphorous doped graphene quantum dots: Excellent flame retardants and smoke suppressants for polyacrylonitrile nanocomposites [J ] . Journal of Hazardous Materials , 2020 , 381 : 121013 .

XUE B X , SHI Y R , ZHANG C Y , et al . Construction of a P–N–Si flame retardant coating on the cotton fabric with the integration of biomass carbon dots and ammonium polyphosphate [J ] . Cellulose , 2022 , 29 : 9469 - 9486 .

SUN P X , ZHANG H J , LENG Y , et al . Construction of flame retardant functionalized carbon dot with insulation, flame retardancy and thermal conductivity in epoxy resin [J ] . Construction and Building Materials , 2024 , 451 : 138853 .

ESMAEILI Y , TOISREKANI F , QAZANFARZADEH Z , et al . Unlocking the potential of green-engineered carbon quantum dots for sustainable packaging biomedical applications and water purification [J ] . Advances in Colloid and Interface Science , 2025 , 338 : 103414 .

XIAO T , WANG Y , WANG H , et al . Anticoagulant and antioxidant properties of hemodialysis membranes modified by hydrogels incorporating carbon dots [J ] . Journal of Membrane Science , 2024 , 692 : 122318 .

DONG X L , AWAK M A , TOMLINSON N , et al . Antibacterial effects of carbon dots in combination with other antimicrobial reagents [J ] . Plos One , 2017 , 12 ( 9 ): 185324 .

ZHAO X Q , WANG L , REN S M , et al . One-pot synthesis of Forsythia@carbon quantum dots with natural anti-wood rot fungus activity [J ] . Materials & Design , 2021 , 206 : 109800 .

WANG Z X , WANG Z H , WU F G . Carbon dots as drug delivery vehicles for antimicrobial applications:A minireview [J ] . ChemMedChem , 2022 , 17 ( 13 ): 202200003 .

GAYEN B , PALCHOUDHURY S , CHOWDHURY J . Carbon dots: A mystic star in the world of nanoscience [J ] . Journal of Nanomaterials , 2019 ( 1 ): 3451307 .

AGGARWAL M , PANIGRAHI H , KOTNEES D K , et al . Multifunctional self-healing carbon dot–gelatin bioadhesive: Improved tissue adhesion with simultaneous drug delivery, optical tracking, and photoactivated sterilization [J ] . Biomacromolecules , 2024 , 25 ( 5 ): 3178 - 3189 .

XU L L , ZHANG Q Q , XU Y Z , et al . Functional modification and antibacterial evaluation of orthodontic adhesives with poly (lysine)-derived carbon dots [J ] . RSC Advances , 2025 , 15 : 5876 - 5888 .

YANG P , ZHU Z Q , WANG L , et al . Developing carbon dots as green modifiers for improving the bonding performance of low-molar-ratio urea-formaldehyde resin [J ] . International Journal of Adhesion and Adhesives , 2023 , 125 : 103416 .

ZHANG L Y , WANG W , JIN P , et al . Reactive carbon dots/polysiloxane composites cross-linked silicone resin adhesives for stable white LED constructing [J ] . Composites Communications , 2025 , 53 : 102172 .

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