浸渍改性提高速生材尺寸稳定性的研究进展

王永贵; 于凡钧; 赵怡杰; 肖泽芳; 谢延军

doi:10.12326/j.2096-9694.2024091

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浸渍改性提高速生材尺寸稳定性的研究进展
Research Progress on Impregnation to Improve the Dimensional Stability of Fast-Growing Wood
东北林业大学材料科学与工程学院
木质新型材料教育部工程研究中心，黑龙江哈尔滨，150040
2025年39卷第1期页码：10-21
DOI： 10.12326/j.2096-9694.2024091
稿件说明：

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王永贵,于凡钧,赵怡杰等.浸渍改性提高速生材尺寸稳定性的研究进展[J].木材科学与技术,2025,39(01):10-21. DOI： 10.12326/j.2096-9694.2024091.

WANG Yonggui,YU Fanjun,ZHAO Yijie,et al.Research Progress on Impregnation to Improve the Dimensional Stability of Fast-Growing Wood[J].Chinese Journal of Wood Science and Technology,2025,39(01):10-21. DOI： 10.12326/j.2096-9694.2024091.

摘要

利用木材改性技术提升速生材的材质是缓解木材短缺问题的关键途径之一。浸渍改性技术通过改变木材细胞壁结构和/或填充细胞腔，不仅能有效提高木材的尺寸稳定性、耐久性和力学性能，还赋予木材阻燃、耐腐防虫等功能。常用的改性剂包括热固性树脂、有机单体、生物质基改性剂和有机/无机复合改性剂等。改性剂提升木材尺寸稳定性的机理主要包括改性剂充胀细胞壁、降低水分吸附并阻止水分子进入木材，从而提升抗干缩湿胀的能力。生物质基改性剂，如糠醇树脂、小分子糖和木质素因其环保性和可降解性受到关注，提升木材性能，减少对化石资源的依赖。为进一步提升改性效果，建议未来的发展方向聚焦于新型改性剂的合成和改性工艺的优化，同时借助人工智能技术实现改性过程优化、性能预测和参数调整等。

Abstract

The improvement of wood quality through modification techniques is one of the key strategies to alleviate the challenge of wood resource shortage. Among various wood modification methods

impregnation is particularly effective. This technique alters the structure of the wood cell wall and/or fills the cell lumen

thereby significantly enhancing the dimensional stability

durability

and mechanical properties of the wood. Additionally

it enhances functional characteristics such as fire retardancy and resistance to decay and insect infestation. Common modifiers include thermosetting resins

organic monomers

biomass-based modifiers

and organic-inorganic compound modifiers. The mechanisms by which these modifiers enhance dimensional stability primarily involve the swelling of the wood cell wall

the reduction of water absorption

and the prevention of water molecules from entering the wood

thereby improving resistance to shrinkage and swelling. Biomass-based modifiers such as furfuryl alcohol resins

small-molecule sugars

and lignin have attracted significant attention due to their environment-friendly and biodegradable properties. These modifiers not only enhance wood performance but also reduce the dependence on fossil resources. To further improve modification effectiveness

future research needs to focus on the synthesis of novel modifiers and the optimization of modification processes. Furthermore

leveraging artificial intelligence

it can be achieved to optimize the modification process

predict performance

and calibrate parameters.

关键词

Keywords

references

王志海 , 舒勇 , 胡小燕 , 等 . 基于中国木材市场谈国家储备林的发展 [J ] . 中南林业调查规划 , 2024 , 43 ( 2 ): 5 - 9 .

WANG Z H , SHU Y , HU X Y , et al . Discussion on the development of the national reserve forest based on Chinese timber market [J ] . Central South Forest Inventory and Planning , 2024 , 43 ( 2 ): 5 - 9 .

菅宁红 , 赵海兰 , 刘珉 . 我国森林资源增长驱动因素及潜力分析 [J ] . 林草政策研究 , 2022 , 2 ( 3 ): 64 - 71 .

吕建雄 , 徐康 , 刘元 , 等 . 速生人工林杨木增强改性的研究进展 [J ] . 中南林业科技大学学报 , 2014 , 34 ( 3 ): 99 - 103 .

LYU J X , XU K , LIU Y , et al . Research progresses on reinforced modifi cation of poplar wood from fastgrowing plantation [J ] . Journal of Central South University of Forestry & Technology , 2014 , 34 ( 3 ): 99 - 103 .

CHEN C J , KUANG Y D , ZHU S Z , et al . Structure–property–function relationships of natural and engineered wood [J ] . Nature Reviews Materials , 2020 , 5 ( 9 ): 642 - 666 .

谢延军 , 符启良 , 王清文 , 等 . 木材化学功能改良技术进展与产业现状 [J ] . 林业科学 , 2012 , 48 ( 9 ): 154 - 163 .

XIE Y J , FU Q L , WANG Q W , et al . Wood chemical modification: the state of the art of technologies and commercialization [J ] . Scientia Silvae Sinicae , 2012 , 48 ( 9 ): 154 - 163 .

符启良 . 氮羟甲基树脂/醇功能改良杨木力学性能的研究 [D ] . 哈尔滨 : 东北林业大学 , 2013 .

陈宣宗 . 酚醛树脂浸渍改性马尾松木材细胞壁结构及性能研究 [D ] . 南京 : 南京林业大学 , 2019 .

左迎峰 , 吴义强 , 张新荔 , 等 . 低分子量酚醛树脂浸渍人工林木材研究进展 [J ] . 材料导报 , 2015 , 29 ( 23 ): 7 - 11 .

ZUO Y F , WU Y Q , ZHANG X L , et al . Progress on plantation wood impregnated with low molecular weight phenol-formaldehyde resin [J ] . Materials Reports , 2015 , 29 ( 23 ): 7 - 11 .

赵洋 . 浸渍、高温及协同处理对中山杉木材性能的影响 [D ] . 南京 : 南京林业大学 , 2022 .

ANG A F , ASHAARI Z , BAKAR E S , et al . Possibility of enhancing the dimensional stability of jelutong ( Dyera costulata ) wood using glyoxalated alkali lignin-phenolic resin as bulking agent [J ] . European Journal of Wood and Wood Products , 2018 , 76 ( 1 ): 269 - 282 .

GAO Z H , LI D . Chemical modification of poplar wood with foaming polyurethane resins [J ] . Journal of Applied Polymer Science , 2007 , 104 ( 5 ): 2980 - 2985 .

ALTUN S , TOKDEMIR V . Modification with melamine formaldehyde and melamine-urea formaldehyde resin to improve the physical and mechanical properties of wood [J ] . BioResources , 2016 , 12 ( 1 ): 586 - 596 .

覃引鸾 , 李建章 , 李萍 . 不同合成树脂工艺对改性材性能影响研究 [J ] . 西北林学院学报 , 2021 , 36 ( 4 ): 198 - 203 .

QIN Y L , LI J Z , LI P . Effects of different synthetic resin processes on the properties of modified wood [J ] . Journal of Northwest Forestry University , 2021 , 36 ( 4 ): 198 - 203 .

李文环 . 三聚氰胺浸渍树脂胶共聚改性及性能研究 [D ] . 杭州 : 浙江农林大学 , 2016 .

YAO M M , YANG Y Q , SONG J L , et al . Melamine formaldehyde modified furfurylation to improve Chinese fir’s dimensional stability and mechanical properties [J ] . BioResources , 2017 , 12 ( 2 ): 3057 - 3066 .

ALTGEN M , AWAIS M , ALTGEN D , et al . Distribution and curing reactions of melamine formaldehyde resin in cells of impregnation-modified wood [J ] . Scientific Reports , 2020 , 10 : 3366 .

LIU Q Q , DU H J , LYU W H . Physical and mechanical properties of poplar wood modified by glucose-urea-melamine resin/sodium silicate compound [J ] . Forests , 2021 , 12 ( 2 ): 127 .

PING L J , CHAI Y B , SUN B L , et al . Assessment of the physico-mechanical, thermal, and morphological properties of rubber wood modified with silica Sol in combination with GU/GMU resins [J ] . BioResources , 2020 , 15 ( 4 ): 8051 - 8064 .

GÉRARDIN P . New alternatives for wood preservation based on thermal and chemical modification of wood：a review [J ] . Annals of Forest Science , 2016 , 73 ( 3 ): 559 - 570 .

仇洪波 , 李改云 , 范东斌 , 等 . 水性乙烯基单体接枝共聚改善杨木性能的研究 [J ] . 木材工业 , 2018 , 32 ( 5 ): 6 - 10 .

QIU H B , LI G Y , FAN D B , et al . Performance of modified poplar wood by graft copolymerization with water soluble vinyl monomer [J ] . China Wood Industry , 2018 , 32 ( 5 ): 6 - 10 .

MATTOS B , SERRANO L , GATTO D , et al . Thermochemical and hygroscopicity properties of pinewood treated by in situ copolymerisation with methacrylate monomers [J ] . Thermochimica Acta , 2014 , 596 : 70 - 78 .

郭登康 , 郭耐 , 傅峰 , 等 . 有机物改性增强木材物理力学性能的研究进展 [J ] . 材料导报 , 2023 , 37 ( 22 ): 266 - 276 .

GUO D K , GUO N , FU F , et al . Research progress on improving physical and mechanical properties of wood by organic modification [J ] . Materials Reports , 2023 , 37 ( 22 ): 266 - 276 .

ACOSTA A P , DE AVILA DELUCIS R , AMICO S C , et al . Fast-growing pine wood modified by a two-step treatment based on heating and in situ polymerization of polystyrene [J ] . Construction and Building Materials , 2021 , 302 : 124422 .

SANGREGORIO A , MURALIDHARA A , GUIGO N , et al . Humin based resin for wood modification and property improvement [J ] . Green Chemistry , 2020 , 22 ( 9 ): 2786 - 2798 .

SHEN X S , YANG S , LI G Y , et al . The contribution mechanism of furfuryl alcohol treatment on the dimensional stability of plantation wood [J ] . Industrial Crops and Products , 2022 , 186 : 115143 .

冷魏祺 , 何盛 , 张雪峰 , 等 . 糠醇树脂改性木材机制的研究进展与思考 [J ] . 林业工程学报 , 2021 , 6 ( 6 ): 35 - 43 .

LENG W Q , HE S , ZHANG X F , et al . Research progress and thoughts on the modification mechanism of wood furfurylation [J ] . Journal of Forestry Engineering , 2021 , 6 ( 6 ): 35 - 43 .

OHMAE K , MINATO K , NORIMOTO M . The analysis of dimensional changes due to chemical treatments and water soaking for hinoki ( Chamaecyparis obtusa ) wood [J ] . Holzforschung , 2002 , 56 ( 1 ): 98 - 102 .

SHEN X S , GUO D K , JIANG P , et al . Water vapor sorption mechanism of furfurylated wood [J ] . Journal of Materials Science , 2021 , 56 ( 19 ): 11324 - 11334 .

沈晓双 , 邹献武 , 李改云 . 糠醇树脂木材改性技术研究进展 [J ] . 木材工业 , 2017 , 31 ( 3 ): 27 - 30 .

SHEN X S , ZOU X W , LI G Y . Review of wood modification technology with furfuryl alcohol resin [J ] . China Wood Industry , 2017 , 31 ( 3 ): 27 - 30 .

LI W J , LIU M H , WANG H K , et al . Fabrication of highly stable and durable furfurylated wood materials. Part I: process optimization [J ] . Holzforschung , 2020 , 74 ( 12 ): 1135 - 1146 .

YANG T T , WANG J M , XU J Q , et al . Hygroscopicity and dimensional stability of Populus eurameri cana Cv. modified by furfurylation combined with low hemicellulose pretreatment [J ] . Journal of Materials Science , 2019 , 54 ( 20 ): 13445 - 13456 .

杨茗麟 , 肖泽芳 , 王海刚 , 等 . 柠檬酸与蔗糖改性杉木的物理性能 [J ] . 东北林业大学学报 , 2021 , 49 ( 12 ): 120 - 125 .

YANG M L , XIAO Z F , WANG H G , et al . Physical properties of Chinese fir wood modified with the mixing agent of citric acid and sucrose [J ] . Journal of Northeast Forestry University , 2021 , 49 ( 12 ): 120 - 125 .

GUO W J , XIAO Z F , WENTZEL M , et al . Modification of Scots pine with activated glucose and citric acid: physical and mechanical properties [J ] . BioResources , 2019 , 14 ( 2 ): 3445 - 3458 .

郭文岩 . 羧基化蔗糖分子改性木材研究 [D ] . 杭州 : 浙江农林大学 , 2023 .

郭文君 . 活化葡萄糖基处理剂制备及改性木材性能和机理研究 [D ] . 哈尔滨 : 东北林业大学 , 2019 .

刘娜 . 葡萄糖和氮羟甲基树脂改性杨木的探索研究 [D ] . 哈尔滨 : 东北林业大学 , 2014 .

ŠEFC B , TRAJKOVIĆ J , HASAN M , et al . Dimensional stability of wood modified by citric acid using different catalysts [J ] . Drvna Industrija , 2009 , 60 ( 1 ): 23 .

KURKOWIAK K , EMMERICH L , MILITZ H . Wood chemical modification based on bio-based polycarboxylic acid and polyols–status quo and future perspectives [J ] . Wood Material Science & Engineering , 2022 , 17 ( 6 ): 1040 - 1054 .

FENG X H , XIAO Z F , SUI S J , et al . Esterification of wood with citric acid: the catalytic effects of sodium hypophosphite (SHP) [J ] . Holzforschung , 2014 , 68 ( 4 ): 427 - 433 .

BECK G . Leachability and decay resistance of wood polyesterified with sorbitol and citric acid [J ] . Forests , 2020 , 11 ( 6 ): 650 .

L’HOSTIS C , THÉVENON M F , FREDON E , et al . Improvement of beech wood properties by in situ formation of polyesters of citric and tartaric acid in combination with glycerol [J ] . Holzforschung , 2018 , 72 ( 4 ): 291 - 299 .

HE X Y , XIAO Z F , FENG X H , et al . Modification of poplar wood with glucose crosslinked with citric acid and 1, 3-dimethylol-4, 5-dihydroxy ethyleneurea [J ] . Holzforschung , 2016 , 70 ( 1 ): 47 - 53 .

KARTHÄUSER J , BIZIKS V , MAI C , et al . Lignin and lignin-derived compounds for wood applications—a review [J ] . Molecules , 2021 , 26 ( 9 ): 2533 .

ZHOU H Z , LI J Y , MA E N . Multiscale modification of Populus cathayana by alkali lignin combined with heat treatment [J ] . Polymers , 2018 , 10 ( 11 ): 1240 .

GAO Z Z , WANG W J , YU F J , et al . Improved dimensional stability and mechanical properties of rubberwood via modification with maleated lignin and densification [J ] . Holzforschung , 2023 , 77 ( 3 ): 170 - 183 .

YU F J , BA Z C , GAO Z Z , et al . Modification with lignin-based N-P flame retardant to improve the flame retardancy and smoke suppression of wood [J ] . Chemical Engineering Journal , 2024 , 493 : 152827 .

YU F J , YOU Z Y , MA Y S , et al . Modification with carboxymethylation-activated alkali lignin/glutaraldehyde hybrid modifier to improve physical and mechanical properties of fast-growing wood [J ] . Wood Science and Technology , 2023 , 57 ( 3 ): 583 - 603 .

XUE Q X , DONG Y M , ZHAO Y F , et al . Physical-mechanical properties and weathering performance of poplar and spruce wood with various tung oil loadings [J ] . Industrial Crops and Products , 2024 , 221 : 119399 .

KWON O , CHOI Y S , CHOI W , et al . Decay resistance and dimensional stability of wood impregnated with Castor oil using a pressure treatment [J ] . Holzforschung , 2023 , 77 ( 11/12 ): 879 - 888 .

LIU M H , WANG J Y , YAN Q M , et al . Green bio-derived epoxidized linseed-oil plasticizer improves the toughness, strength, and dimensional stability of furfuryl alcohol-modified wood [J ] . Industrial Crops and Products , 2024 , 217 : 118886 .

许吉 , 翟兆兰 , 闫鑫焱 , 等 . 改性松香对速生杨木性能提升的研究 [J ] . 林产化学与工业 , 2020 , 40 ( 2 ): 55 - 62 .

XU J , ZHAI Z L , YAN X Y , et al . Improvement of properties of fast-growing poplar by modified rosin [J ] . Chemistry and Industry of Forest Products , 2020 , 40 ( 2 ): 55 - 62 .

ZHAO Y X , HE L X , KANG J Y , et al . Effects of tannin acid impregnated pretreatment on dimensional stability and chemical composition of heat-treated Chinese fir [J ] . Holzforschung , 2024 , 78 ( 2 ): 127 - 136 .

BI Z J , ZHOU X J , CHEN J , et al . Effects of extracts on color, dimensional stability, and decay resistance of thermally modified wood [J ] . European Journal of Wood and Wood Products , 2024 , 82 ( 2 ): 387 - 401 .

YANG C W , YANG S S , YANG H X , et al . Improvement of the dimensional stability of rubber wood based on the synergies of sucrose and tung oil impregnation [J ] . Forests , 2023 , 14 ( 9 ): 1831 .

WANG Y J , ZHANG R H , YANG M Q , et al . Improvement on dimensional stability and mold resistance of wood modified by tannin acid and tung oil [J ] . Holzforschung , 2022 , 76 ( 10 ): 929 - 940 .

董友明 . 速生杨木细胞壁改性与增强机制 [D ] . 北京 : 北京林业大学 , 2018 .

YANG M S , CHEN X Y , LI J , et al . Preparation of wood with better water-resistance properties by a one-step impregnation of maleic rosin [J ] . Journal of Adhesion Science and Technology , 2018 , 32 ( 21 ): 2381 - 2393 .

WANG J A , MA Y , GAO S L , et al . Improvement of physical and mechanical properties of poplar wood via immobilization of rosin by grafting of vinyl chains [J ] . Journal of Wood Chemistry and Technology , 2021 , 41 ( 6 ): 261 - 268 .

严玉涛 . 乙二醛复合改性速生杨木性能与增强机制研究 [D ] . 北京 : 北京林业大学 , 2017 .

HIMMEL S , MAI C . Effects of acetylation and formalization on the dynamic water vapor sorption behavior of wood [J ] . Holzforschung , 2015 , 69 ( 5 ): 633 - 643 .

SUN W J , SHEN H Y , CAO J Z . Modification of wood by glutaraldehyde and poly (vinyl alcohol) [J ] . Materials & Design , 2016 , 96 : 392 - 400 .

YAN Y T , DONG Y M , LI C , et al . Optimization of reaction parameters and characterization of glyoxal-treated poplar sapwood [J ] . Wood Science and Technology , 2015 , 49 ( 2 ): 241 - 256 .

孙瑾 , 高振忠 , 李秉滔 , 等 . 乙二醛交联处理改性大青杨木材的研究 [J ] . 华南农业大学学报 , 2006 , 27 ( 3 ): 73 - 75 .

SUN J , GAO Z Z , LI B T , et al . Study on modifying Populus ussuriensis wood by glyoxal cross-linking reagents [J ] . Journal of South China Agricultural University , 2006 , 27 ( 3 ): 73 - 75 .

XIAO Z F , XIE Y J , MILITZ H , et al . Effect of glutaraldehyde on water related properties of solid wood [J ] . Holzforschung , 2010 , 64 ( 4 ): 483 - 488 .

XIAO Z F , XIE Y J , MILITZ H , et al . Effects of modification with glutaraldehyde on the mechanical properties of wood [J ] . Holzforschung , 2010 , 64 ( 4 ): 475 - 482 .

孟什 , 冯鑫浩 , 贺晓艳 , 等 . 氮羟甲基树脂改性杨木的涂饰性能 [J ] . 东北林业大学学报 , 2014 , 42 ( 4 ): 96 - 100, 104 .

MENG S , FENG X H , HE X Y , et al . Effect of N-methylol resin on the coating properties of poplar wood [J ] . Journal of Northeast Forestry University , 2014 , 42 ( 4 ): 96 - 100, 104 .

LI W J , CHEN L F , LI X W . Comparison of physical-mechanical and mould-proof properties of furfurylated and DMDHEU-modified wood [J ] . BioResources , 2019 , 14 ( 4 ): 9628 - 9644 .

CAI M Z , FU Z Y , CAI Y C , et al . Effect of impregnation with maltodextrin and 1, 3-dimethylol-4, 5-dihydroxyethyleneurea on poplar wood [J ] . Forests , 2018 , 9 ( 11 ): 676 .

孙振宇 , 张源 , 左迎峰 , 等 . 有机-无机复合改性速生木材研究现状与展望 [J ] . 材料导报 , 2021 , 35 ( 5 ): 5181 - 5187 .

SUN Z Y , ZHANG Y , ZUO Y F , et al . Research status and prospect of organic-inorganic compound modified fast-growing wood [J ] . Materials Reports , 2021 , 35 ( 5 ): 5181 - 5187 .

周亚 , 李萍 , 左迎峰 , 等 . 无机质增强木材研究进展与发展趋势 [J ] . 材料导报 , 2019 , 33 ( 17 ): 2989 - 2996 .

ZHOU Y , LI P , ZUO Y F , et al . Research progress and development trend of inorganic reinforced wood [J ] . Materials Reports , 2019 , 33 ( 17 ): 2989 - 2996 .

SUN Z Y , ZUO Y F , LI P , et al . Hyperbranched organic-inorganic co-modification improves the strength, dimensional stability, and thermal stability of poplar wood [J ] . Industrial Crops and Products , 2023 , 191 : 115923 .

范友华 , 胡伟 , 陈泽君 . 无机物填充改性复合木材的制备及性能研究 [J ] . 林业机械与木工设备 , 2008 , 36 ( 11 ): 18 - 21 .

FAN Y H , HU W , CHEN Z J . Study on preparation and property of inorganic matter filled modified wood composite [J ] . Forestry Machinery & Woodworking Equipment , 2008 , 36 ( 11 ): 18 - 21 .

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