Preparation of Organic-Inorganic Hybrid Modified Soy-based Adhesive and its Application in Three-layer Particleboards

ZENG Guodong; CUI Chen; ZHU Feng; DONG Youming; TANG Yunbiao; LIU Ming; LI Jianzhang

doi:10.12326/j.2096-9694.2025111

GREEN MANUFACTURING OF WOOD-BASED MATERIALS | Views : 0 下载量: CSCD: 0 CNKI被引量: 0 Crossref: 0 Wos: 0 Scopus: 0 更多指标

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Preparation of Organic-Inorganic Hybrid Modified Soy-based Adhesive and its Application in Three-layer Particleboards
1.College of Materials Science and Engineering，Nanjing Forestry University，Nanjing 210037，Jiangsu，China
2.Guangxi Fenglin Wood Industry Group Co.，Ltd.，Nanning 530000，Guangxi，China
3.College of Materials Science and Technology，Beijing Forestry University，Beijing 100083，China
Vol. 39, Issue 5, Pages: 1-9(2025)
DOI： 10.12326/j.2096-9694.2025111
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曾国栋,崔辰,朱峰等.有机-无机杂化改性大豆胶黏剂制备及其在三层结构刨花板中的应用[J].木材科学与技术,2025,39(05):1-9. DOI： 10.12326/j.2096-9694.2025111.

ZENG Guodong,CUI Chen,ZHU Feng,et al.Preparation of Organic-Inorganic Hybrid Modified Soy-based Adhesive and its Application in Three-layer Particleboards[J].Chinese Journal of Wood Science and Technology,2025,39(05):1-9. DOI： 10.12326/j.2096-9694.2025111.

摘要

为了解决大豆胶黏剂耐水性差、易霉变，难以适应刨花板生产工艺的问题，通过二硫化钼纳米片与聚乙烯亚胺协同改性大豆胶黏剂，并将其应用于刨花板制备。结果表明，改性大豆胶黏剂的断面结构更加致密，耐水性提高，室温贮存20 d未发生霉变。制备的三层结构刨花板静曲强度（19.20 MPa）、弹性模量（2.77 GPa）、内胶合强度（0.73 MPa）、表面胶合强度（1.10 MPa）、2 h吸水厚度膨胀率（1.88%）等性能指标均满足GB/T 4897—2015《刨花板》关于P2型刨花板的要求，且防霉等级达到LY/T 2230—2013《人造板防霉性能评价》中1级要求。

Abstract

The application of soy-based adhesives is limited due to its poor water resistance

susceptibility to mildew

and incompatibility with particleboard manufacturing processes. To overcome these shortcomings

this study improved the adhesive’s performance by synergetic modification using MoS

and polyethyleneimine

and tested the physical-mechanical properties and mildew resistance of particleboard. Results showed that the modified soy-based adhesive exhibited a dense fracture structure

improved cohesive strength and water resistance

and excellent mildew resistance. The fabricated three-layer particleboard demonstrated excellent physical and mechanical properties

including a static flexural strength of 19.20 MPa

elastic modulus of 2.77 GPa

internal bonding strength of 0.73 MPa

surface bonding strength of 1.10 MPa

and a 2-h water absorption thickness expansion rate of 1.88%

which met the Type P2 requirements specified in GB/T 4897—2015

Particleboard

. Notably

the particleboard achieved a mildew resistance with an infection grading value exceeding level 1 according to LY/T 2230—2013 S

tandard method of evaluating the resistance of wood-based panels to mold

. These properties demonstrated a great potential of using the modified soy-based adhesive in manufacturing particleboards.

关键词

Keywords

references

张忠涛 . 我国人造板产品消费量超3亿m 3 [J ] . 中国人造板 , 2025 , 32 ( 10 ): 45 - 46 .

ZHANG Z T . The consumption of wood-based panel products in China exceeds 300 million m 3 [J ] . China Wood-based Panels , 2025 , 32 ( 10 ): 45 - 46 .

杨龙 , 毛顺国 , 陆铜华 , 等 . 我国刨花板工业技术进步回顾与展望 [J ] . 木材科学与技术 , 2024 , 38 ( 1 ): 1 - 12 .

YANG L , MAO S G , LU T H , et al . Review and outlook of technology development in China’s particleboard industry [J ] . Chinese Journal of Wood Science and Technology , 2024 , 38 ( 1 ): 1 - 12 .

CHENG Q Z , ESSIEN C , VIA B , et al . Cost savings from soy flour substitution in methylene diphenyl diisocyanate for bonding flakes and particle [J ] . Forest Products Journal , 2019 , 69 ( 2 ): 154 - 158 .

孙博 , 阚雨菲 , 高振华 . HN-PAE树脂对大豆蛋白胶黏剂的共交联改性研究 [J ] . 木材科学与技术 , 2022 , 36 ( 2 ): 54 - 59 .

SUN B , KAN Y F , GAO Z H . Co-crosslinking of soybean adhesive blending with urea-epoxy-polyamidoamine epichlorohydrin resin [J ] . Chinese Journal of Wood Science and Technology , 2022 , 36 ( 2 ): 54 - 59 .

崔政 , 李京超 , 李建章 , 等 . 木材胶黏剂仿生改性研究进展 [J ] . 材料导报 , 2024 , 38 ( 8 ): 274 - 280 .

CUI Z , LI J C , LI J Z , et al . Research progress in the biomimetic modification of wood adhesives [J ] . Materials Reports , 2024 , 38 ( 8 ): 274 - 280 .

徐艳涛 , 刘晴 , 韩宇飞 , 等 . 低黏度大豆蛋白胶黏剂制备及其在刨花板应用 [J ] . 木材科学与技术 , 2022 , 36 ( 3 ): 33 - 39 .

XU Y T , LIU Q , HAN Y F , et al . Development of low viscosity soy protein adhesive for particleboard manufacturing [J ] . Chinese Journal of Wood Science and Technology , 2022 , 36 ( 3 ): 33 - 39 .

BACIGALUPE A , ESCOBAR M M . Soy protein adhesives for particleboard production: a review [J ] . Journal of Polymers and the Environment , 2021 , 29 ( 7 ): 2033 - 2045 .

CHEN S Q , SHI S Q , ZHOU W R , et al . Developments in bio-based soy protein adhesives: a review [J ] . Macromolecular Materials and Engineering , 2022 , 307 ( 10 ): 2200277 .

BAI M Y , CAO J F , LI J Z , et al . Development of soybeans starch based tough, water resistant and mildew-proof adhesives through multiple cross linking cooperation strategy [J ] . Journal of Cleaner Production , 2021 , 321 : 129001 .

ZHAO X D , YANG Y X , YU J , et al . Injectable hydrogels with high drug loading through B-N coordination and ROS-triggered drug release for efficient treatment of chronic periodontitis in diabetic rats [J ] . Biomaterials , 2022 , 282 : 121387 .

KANG H F , WEI W Y , SUN L S , et al . Modular design and bonding mechanism of internal boron–nitrogen coordinated boronic ester hydrogels with alkaline pH responsiveness and tunable gelation pH [J ] . Chemistry of Materials , 2023 , 35 ( 6 ): 2408 - 2420 .

何大方 , 陆俊泓 , 朱晔 , 等 . 中空球形MoS 2 /C复合材料的构筑及储锂性能 [J ] . 常州大学学报(自然科学版) , 2024 , 36 ( 5 ): 1 - 9 .

HE D F , LU J H , ZHU Y , et al . Preparation and lithium-storage properties of hollow sphere MoS 2 /C nanocomposites [J ] . Journal of Changzhou University (Natural Science Edition) , 2024 , 36 ( 5 ): 1 - 9 .

WANG K , LI R , MA J H , et al . Extracting keratin from wool by using l-cysteine [J ] . Green Chemistry , 2016 , 18 ( 2 ): 476 - 481 .

SHI C L , ZENG G D , ZHU F , et al . Highly absorbent polymers-inspired biomass adhesive with enhanced strength and water retention properties [J ] . ACS Sustainable Chemistry & Engineering , 2025 , 13 ( 16 ): 5927 - 5938 .

WANG Y Q , CHEN P C , ZHOU X J , et al . Highly sensitive zwitterionic hydrogel sensor for motion and pulse detection with water retention, adhesive, antifreezing, and self-healing properties [J ] . ACS Applied Materials & Interfaces , 2022 , 14 ( 41 ): 47100 - 47112 .

WAN J S , LI H , CAI X Y , et al . Developing the functional cotton fabric with N-halamine antibacterial structure based on DA/PEI [J ] . Cellulose , 2022 , 29 ( 18 ): 9953 - 9967 .

PARK K , OH Y , PANDA P K , et al . Effects of an acidic catalyst on the barrier and water resistance properties of crosslinked poly (vinyl alcohol) and boric acid films [J ] . Progress in Organic Coatings , 2022 , 173 : 107186 .

BIAN Y Y , BAI M Y , CAO J F , et al . A strong soybean meal adhesive enhanced by aluminum hydroxide nanoparticles via a low-cost and simple organic-inorganic hybrid strategy [J ] . International Journal of Adhesion and Adhesives , 2023 , 125 : 103442 .

ZENG Y C , XU P W , YANG W J , et al . Soy protein-based adhesive with superior bonding strength and water resistance by designing densely crosslinking networks [J ] . European Polymer Journal , 2021 , 142 : 110128 .

LIU B , LI J H , ZHANG Z T , et al . pH responsive antibacterial hydrogel utilizing catechol-boronate complexation chemistry [J ] . Chemical Engineering Journal , 2022 , 441 : 135808 .

王志鹏 , 周如东 , 王东 , 等 . 室温自修复柔性导热Ti 3 C 2 /聚氨酯复合材料的制备及性能研究 [J ] . 涂料工业 , 2025 , 55 ( 6 ): 71 - 75, 82 .

WANG Z P , ZHOU R D , WANG D , et al . Preparation and properties of room-temperature self-healing flexible thermal conductive Ti 3 C 2 /polyurethane composites [J ] . Paint & Coatings Industry , 2025 , 55 ( 6 ): 71 - 75, 82 .

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