Preparation and Performance Characterization of Paulownia Wood Modified Using Bleaching-Impregnation-Hot Pressing Synergistic Method

LIANG Bonan; ZHANG Kun; LIU Suling; LIU Xiaozhen; LI Xueqi; FAN Xueqin; ZHANG Yang; GAN Wentao

doi:10.12326/j.2096-9694.2025058

RESEARCH PAPERS | Views : 0 下载量: 36 CSCD: 0 CNKI被引量: 0 Crossref: 0 Wos: 0 Scopus: 0 更多指标

PDF
Export
Share
Collection
Album

Preparation and Performance Characterization of Paulownia Wood Modified Using Bleaching-Impregnation-Hot Pressing Synergistic Method
College of Materials Science and Engineering，Northeast Forestry University，Key Laboratory of Biomass Materials Science and Technology，Ministry of Education，Harbin 150040，Heilongjiang，China
Vol. 39, Issue 6, Pages: 43-52(2025)
DOI： 10.12326/j.2096-9694.2025058
稿件说明：

移动端阅览

梁博楠,张坤,刘苏玲等.漂白-浸渍-热压协同改性泡桐木材的制备及性能表征[J].木材科学与技术,2025,39(06):43-52. DOI： 10.12326/j.2096-9694.2025058.

LIANG Bonan,ZHANG Kun,LIU Suling,et al.Preparation and Performance Characterization of Paulownia Wood Modified Using Bleaching-Impregnation-Hot Pressing Synergistic Method[J].Chinese Journal of Wood Science and Technology,2025,39(06):43-52. DOI： 10.12326/j.2096-9694.2025058.

摘要

以白花泡桐（

Paulownia fortunei

）木材为研究对象，采用过氧化氢漂白处理，增加木材细胞壁的活性基团数量；利用壳聚糖溶液（质量分数4%）在木材细胞壁上负载有机层，通过涂覆硅酸钠溶液（质量分数40%）形成改性层，在80 ℃和5 MPa的热压条件下固化获得协同改性木材。与天然木材相比，在增重率为18.9%、压缩率为75%时，协同改性木材的拉伸、抗弯强度和硬度分别提升202%、122%和75%；垂直燃烧等级达到V-0级，极限氧指数高达50.1%，热释放速率峰值降低60.1%，总热释放量和总

烟释放量分别减少44.7%和95.1%，一氧化碳释放量下降31.2%；对黑曲霉的防治效力可达100%。该研究为改善速生材材质提供新途径，制备的改性木材在防火安全工程和结构建筑领域具有潜在的应用价值。

Abstract

Paulownia fortunei

suffers from insufficient tensile strength

high flammability

and susceptibility to mold

which severely limit its application in furniture and architectural decoration materials. To address these issues

this study proposes a synergistic method combing bleaching

impregnation

and hot pressing. First

Paulownia fortunei

was bleached with 30% hydrogen peroxide(H

) for 3 hours

preserving its natural porous structure and partial lignin content while increasing interfacial binding sites. The bleached wood was subsequently immersed in a 4% chitosan (CS) solution under a vacuum of －0.1 MPa for 30 minutes. Afterwards

a 40% sodium silicate (Na

SiO

) solution was uniformly applied to the wood surface. Finally

the impregnated wood was cured and densified through hot pressing at 80 ℃ under 5 MPa. The modified wood showed increases in tensile strength

bending strength and hardness of 202%

122% and 75%

respectively

compared to natural wood

with a weight gain of 18.9% and a compression rate of 75%. Regarding flame retardancy

the vertical burning rating reached V-0

the limiting oxygen index (LOI) was 50.1%

the peak heat release rate (HRR) decreased by 60.1%

total heat release (THR) and total smoke release (TSR) decreased by 44.7% and 95.1%

respectively

and carbon monoxide release (COP) decreased by 31.2%. In terms of anti-corrosion performance

this material can effectively resist

Aspergillus niger

with the mold-infected area of 0

achieving 100% mold control efficiency (MCE). This study provided a novel approach for improving the quality of fast-growing wood

and the resulting modified wood shows significant potential for applications in fire safety engineering and structural construction.

关键词

Keywords

references

吴义强 . 木材科学与技术研究新进展 [J ] . 中南林业科技大学学报 , 2021 , 41 ( 1 ): 1 - 28 .

WU Y Q . Newly advances in wood science and technology [J ] . Journal of Central South University of Forestry & Technology , 2021 , 41 ( 1 ): 1 - 28 .

DONG X , GAN W , SHANG Y , et al . Low-value wood for sustainable high-performance structural materials [J ] . Nature Sustainability , 2022 , 5 ( 7 ): 628 - 635 .

ZHANG K , ZHAI W , CAO Z , et al . A sustainable pore wall strengthening for strong and fire-retardant nanopolymerised wood [J ] . Chemical Engineering Journal , 2024 , 480 : 147971 .

DENG Z , LIAO C , LI X , et al . Constructing a multi-crosslinked network of metal coordination and chemical bonding synergy to achieve high strength and super toughness of biobased composites [J ] . Composites Part B: Engineering , 2025 , 275 : 112206 .

LI W , XU X , HAO D , et al . Superwetting-enabled in situ silicification for artificial silicified wood [J ] . Advanced Materials , 2025 : 2501520 .

WANG C , CUI M , XUE J , et al . Fabrication of silica-based superhydrophobic coatings with remarkable wear resistance, corrosion inhibition ability and thermal stability [J ] . Applied Surface Science , 2025 , 161681 .

LI H , WANG C , YANG T , et al . Mineralizing wood with chitosan-silica to enhance the flame retardant and physical-mechanical properties [J ] . Journal of Sol-Gel Science and Technology , 2023 , 107 ( 1 ): 57 - 69 .

XIA Q Q , CHEN C J , LI T , et al . Solar-assisted fabrication of large-scale, patternable transparent wood [J ] . Science Advances , 2021 , 7 ( 5 ): eabd7342 .

ZHANG J , CHENG X , CHANG L , et al . Combined treatments of chitosan and sodium silicate to inhibit alternaria pathogens of postharvest winter jujube [J ] . Food Science and Biotechnology , 2021 , 30 ( 4 ): 589 - 597 .

XUAN L N , FU Y L , LIU Z G . Hydrophobicity and photocatalytic activity of a wood surface coated with a Fe 3+ Doped SiO 2 /TiO 2 film [J ] . Materials , 2018 , 11 : 259433 .

ZHAI L , WANG Y , PENG F , et al . Synthesis of TiO 2 -SiO 2 / waterborne polyurethane hybrid with amino-siloxane terminated via a sol-gel process [J ] . Materials Letters , 2012 , 10 : 81 - 85 .

李坚 , 甘文涛 , 陈志俊 , 等 . 向新出发，木材科学前沿发展 [J ] . 森林工程 , 2025 , 41 ( 1 ): 1 - 39 .

LI J , GAN W T , CHEN Z J , et al . Embarking on a new journey: frontier developments in wood science [J ] . Forest Engineering , 2025 , 41 ( 1 ): 1 - 39 .

CHO W , SHIELDS J R , DUBRULLE L , et al . Ion-complexed chitosan formulations as effective fire-retardant coatings for wood substrates [J ] . Polymer Degradation and Stability , 2022 , 197 : 109870 .

ZHAO F , TANG T , HOU S , et al . Preparation and synergistic effect of chitosan/sodium Phytate/MgO nanoparticle fire-retardant coatings on wood substrate through layer-by-layer self-assembly [J ] . Coatings , 2020 , 10 ( 9 ): 848 .

CHEN J R , ZHOU Z N , MIAO Y , et al . Preparation of CS@BAC composite aerogel with excellent flame-retardant performance, good filtration for PM2.5 and strong adsorption for formaldehyde [J ] . Process Safety and Environmental Protection , 2023 , 173 : 354 - 365 .

陈世尧 , 袁光明 , 杨涛 , 等 . 壳聚糖-SiO 2 仿生物矿化协同改性尾巨桉木材 [J ] . 材料导报 , 2020 , 34 ( 10 ): 10182 - 10186 .

CHEN S Y , YUAN G M , YANG T , et al . Chitosan-SiO 2 biomimetic mineralization synergistic modification of Eucalyptus urophylla wood [J ] . Materials Review , 2020 , 34 ( 10 ): 10182 - 10186 .

GAN W , CHEN C , WANGZ , et al . Dense, self-formed char layer enables a fireretardant wood structural material [J ] . Advanced Functional Materials , 2019 , 29 ( 14 ): 1807444 .

ZHOU H , WEN D , HAO X , et al . Nanostructured multifunctional wood hybrids fabricated via in situ mineralization of zinc borate in hierarchical wood structures [J ] . Chemical Engineering Journal , 2023 , 451 : 138308 .

LI J , LIU Y , ZHANG J , et al . Enhanced fire-retardant, smoke-suppressing, and ultra-strong mechanical properties of non-adhesive laminated wood through borate ion crosslinking [J ] . Industrial Crops and Products , 2025 , 224 : 120412 .

HUANG Y , ZHENG Z , CHEN C , et al . Effective strategy for fabricating surface impregnated and unilaterally densified wood with furfuryl alcohol/flame retardants for enhanced mechanical performance and flame retardancy [J ] . European Journal of Wood and Wood Products , 2024 , 82 ( 3 ): 731 - 745 .

YANG S , WANG Z , LIU Z , et al . Enhancing durable fire safety and anti-corrosion performance of wood through controlled in-situ self-assembly synthesis of Ag-PW nanospheres [J ] . Chemical Engineering Journal , 2023 , 475 : 145227 .

YU C Z , CHEN Y , ZHU Y , et al . Dynamic covalent bonds enabled recyclable chitosan oligosaccharide-based wood adhesive with high adhesion and anti-mildew performances [J ] . International Journal of Biological Macromolecules , 2024 , 137434 .

KUAI B B , XU Q , ZHAN T Y , et al . Development of super dimensional stable poplar structure with fire and mildew resistance by delignification/densification of wood with highly aligned cellulose molecules [J ] . International Journal of Biological Macromolecules , 2024 , 128572 .

Alert me when the article has been cited

提交

Allocation Method of Solid Wood Furniture Components Based on Collaborative Optimization of Wood Texture and Mechanical Properties

Effects of Veneer Hole Repair Methods on Mechanical Properties of Plywood

Preparation and Properties of Coextruded PVC Foamed Wood Plastic-Laminated Veneer Lumber Composites

Preparation of Organic-Inorganic Hybrid Modified Soy-based Adhesive and its Application in Three-layer Particleboards

Effects of Stitching Technique and Lay-Up Configuration on Mechanical Properties of Bamboo Strip Composites